One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction
We are reporting the structural and magnetic characterization of a Mn(III) mononuclear complex based on a Schiff-base ligand with carboxylate pendant arm. Very strong symmetric H-interaction drives a one dimensional organization of this complex, densely packed through C–H⋯π further interactions. Low...
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Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v453_n_p692_Lazzarini http://hdl.handle.net/20.500.12110/paper_00201693_v453_n_p692_Lazzarini |
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paper:paper_00201693_v453_n_p692_Lazzarini2023-06-08T14:40:55Z One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction Albores, Pablo Magnetic properties Manganese(III) One dimensional chain Schiff base Symmetric H-bond We are reporting the structural and magnetic characterization of a Mn(III) mononuclear complex based on a Schiff-base ligand with carboxylate pendant arm. Very strong symmetric H-interaction drives a one dimensional organization of this complex, densely packed through C–H⋯π further interactions. Low temperature magnetic behaviour appears governed by local ion zero field splitting obscuring any possible weak exchange interaction through the symmetric H-bond pathway. © 2016 Elsevier B.V. Fil:Alborés, P. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2016 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v453_n_p692_Lazzarini http://hdl.handle.net/20.500.12110/paper_00201693_v453_n_p692_Lazzarini |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Magnetic properties Manganese(III) One dimensional chain Schiff base Symmetric H-bond |
spellingShingle |
Magnetic properties Manganese(III) One dimensional chain Schiff base Symmetric H-bond Albores, Pablo One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction |
topic_facet |
Magnetic properties Manganese(III) One dimensional chain Schiff base Symmetric H-bond |
description |
We are reporting the structural and magnetic characterization of a Mn(III) mononuclear complex based on a Schiff-base ligand with carboxylate pendant arm. Very strong symmetric H-interaction drives a one dimensional organization of this complex, densely packed through C–H⋯π further interactions. Low temperature magnetic behaviour appears governed by local ion zero field splitting obscuring any possible weak exchange interaction through the symmetric H-bond pathway. © 2016 Elsevier B.V. |
author |
Albores, Pablo |
author_facet |
Albores, Pablo |
author_sort |
Albores, Pablo |
title |
One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction |
title_short |
One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction |
title_full |
One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction |
title_fullStr |
One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction |
title_full_unstemmed |
One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction |
title_sort |
one dimensional mn(iii) schiff-base complex organization through very strong symmetrical h-bond interaction |
publishDate |
2016 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v453_n_p692_Lazzarini http://hdl.handle.net/20.500.12110/paper_00201693_v453_n_p692_Lazzarini |
work_keys_str_mv |
AT alborespablo onedimensionalmniiischiffbasecomplexorganizationthroughverystrongsymmetricalhbondinteraction |
_version_ |
1768546331559723008 |