Synthesis and structure of two polymeric barium-oxydiacetates: [Ba(oda)·H2O]n and [Ba(Hoda)2] n (H2oda: Oxydiacetic acid)

The reaction of barium carbonate or hydroxide with oxydiacetic acid leads to the self-assembly of two barium oxydiacetate polymers in good yield: [Ba(oda)·H2O]n (1) and [Ba(Hoda)2] n (2). The products have been characterized by elemental analysis, IR, TGA and single crystal X-ray diffraction studies...

Descripción completa

Detalles Bibliográficos
Autor principal: Perec, Mireille
Publicado: 2004
Materias:
Barium complexes
Carboxylates
Crystal Structures
Hydrogen bonds
acetoacetic acid derivative
barium derivative
article
atom
conformation
crystal structure
hydrogen bond
infrared spectroscopy
molecular interaction
structure analysis
X ray diffraction
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v357_n7_p2185_Baggio
http://hdl.handle.net/20.500.12110/paper_00201693_v357_n7_p2185_Baggio
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_00201693_v357_n7_p2185_Baggio
record_format dspace
spelling paper:paper_00201693_v357_n7_p2185_Baggio2023-06-08T14:40:51Z Synthesis and structure of two polymeric barium-oxydiacetates: [Ba(oda)·H2O]n and [Ba(Hoda)2] n (H2oda: Oxydiacetic acid) Perec, Mireille Barium complexes Carboxylates Crystal Structures Hydrogen bonds acetoacetic acid derivative barium derivative article atom conformation crystal structure hydrogen bond infrared spectroscopy molecular interaction structure analysis X ray diffraction The reaction of barium carbonate or hydroxide with oxydiacetic acid leads to the self-assembly of two barium oxydiacetate polymers in good yield: [Ba(oda)·H2O]n (1) and [Ba(Hoda)2] n (2). The products have been characterized by elemental analysis, IR, TGA and single crystal X-ray diffraction studies. The central barium atom in each mononuclear fragment is nine-coordinate in 1 and 10-coordinate in 2. These fragments are bridged by carboxylato groups in anti-anti conformation and through H-bonds bonding interactions forming complex 3D networks. © 2003 Elsevier B.V. All rights reserved. Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2004 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v357_n7_p2185_Baggio http://hdl.handle.net/20.500.12110/paper_00201693_v357_n7_p2185_Baggio
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Barium complexes
Carboxylates
Crystal Structures
Hydrogen bonds
acetoacetic acid derivative
barium derivative
article
atom
conformation
crystal structure
hydrogen bond
infrared spectroscopy
molecular interaction
structure analysis
X ray diffraction
spellingShingle Barium complexes
Carboxylates
Crystal Structures
Hydrogen bonds
acetoacetic acid derivative
barium derivative
article
atom
conformation
crystal structure
hydrogen bond
infrared spectroscopy
molecular interaction
structure analysis
X ray diffraction
Perec, Mireille
Synthesis and structure of two polymeric barium-oxydiacetates: [Ba(oda)·H2O]n and [Ba(Hoda)2] n (H2oda: Oxydiacetic acid)
topic_facet Barium complexes
Carboxylates
Crystal Structures
Hydrogen bonds
acetoacetic acid derivative
barium derivative
article
atom
conformation
crystal structure
hydrogen bond
infrared spectroscopy
molecular interaction
structure analysis
X ray diffraction
description The reaction of barium carbonate or hydroxide with oxydiacetic acid leads to the self-assembly of two barium oxydiacetate polymers in good yield: [Ba(oda)·H2O]n (1) and [Ba(Hoda)2] n (2). The products have been characterized by elemental analysis, IR, TGA and single crystal X-ray diffraction studies. The central barium atom in each mononuclear fragment is nine-coordinate in 1 and 10-coordinate in 2. These fragments are bridged by carboxylato groups in anti-anti conformation and through H-bonds bonding interactions forming complex 3D networks. © 2003 Elsevier B.V. All rights reserved.
author Perec, Mireille
author_facet Perec, Mireille
author_sort Perec, Mireille
title Synthesis and structure of two polymeric barium-oxydiacetates: [Ba(oda)·H2O]n and [Ba(Hoda)2] n (H2oda: Oxydiacetic acid)
title_short Synthesis and structure of two polymeric barium-oxydiacetates: [Ba(oda)·H2O]n and [Ba(Hoda)2] n (H2oda: Oxydiacetic acid)
title_full Synthesis and structure of two polymeric barium-oxydiacetates: [Ba(oda)·H2O]n and [Ba(Hoda)2] n (H2oda: Oxydiacetic acid)
title_fullStr Synthesis and structure of two polymeric barium-oxydiacetates: [Ba(oda)·H2O]n and [Ba(Hoda)2] n (H2oda: Oxydiacetic acid)
title_full_unstemmed Synthesis and structure of two polymeric barium-oxydiacetates: [Ba(oda)·H2O]n and [Ba(Hoda)2] n (H2oda: Oxydiacetic acid)
title_sort synthesis and structure of two polymeric barium-oxydiacetates: [ba(oda)·h2o]n and [ba(hoda)2] n (h2oda: oxydiacetic acid)
publishDate 2004
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v357_n7_p2185_Baggio
http://hdl.handle.net/20.500.12110/paper_00201693_v357_n7_p2185_Baggio
work_keys_str_mv AT perecmireille synthesisandstructureoftwopolymericbariumoxydiacetatesbaodah2onandbahoda2nh2odaoxydiaceticacid
_version_ 1768544806634520576

Ejemplares similares