Novel europium and gadolinium compounds in the lanthanide(III) oxydiacetate series
Three new lanthanide oxydiacetate compounds have been prepared and their structures determined by single crystal X-ray methods: {[Ln2(oda)3(H2O)2]·5H2O}(n) (Ln = Eu, Gd) and [Eu(oda)(Hoda)(H2O)]·2H2O. The former are orthorhombic and Ama2, with LnO8 and LnO9 cores bridged by anti-anti carboxylate lig...
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2000
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v303_n2_p306_Aramendia http://hdl.handle.net/20.500.12110/paper_00201693_v303_n2_p306_Aramendia |
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paper:paper_00201693_v303_n2_p306_Aramendia2023-06-08T14:40:49Z Novel europium and gadolinium compounds in the lanthanide(III) oxydiacetate series Crystal structures Lanthanide complexes Luminescence acetoacetic acid europium gadolinium lanthanide article chemical structure crystal structure ligand binding luminescence solid state X ray analysis Three new lanthanide oxydiacetate compounds have been prepared and their structures determined by single crystal X-ray methods: {[Ln2(oda)3(H2O)2]·5H2O}(n) (Ln = Eu, Gd) and [Eu(oda)(Hoda)(H2O)]·2H2O. The former are orthorhombic and Ama2, with LnO8 and LnO9 cores bridged by anti-anti carboxylate ligands and the latter is mononuclear containing a EuO9 core. Luminescence spectra of the europium complexes in the solid state are presented. (C) 2000 Elsevier Science S.A. 2000 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v303_n2_p306_Aramendia http://hdl.handle.net/20.500.12110/paper_00201693_v303_n2_p306_Aramendia |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Crystal structures Lanthanide complexes Luminescence acetoacetic acid europium gadolinium lanthanide article chemical structure crystal structure ligand binding luminescence solid state X ray analysis |
| spellingShingle |
Crystal structures Lanthanide complexes Luminescence acetoacetic acid europium gadolinium lanthanide article chemical structure crystal structure ligand binding luminescence solid state X ray analysis Novel europium and gadolinium compounds in the lanthanide(III) oxydiacetate series |
| topic_facet |
Crystal structures Lanthanide complexes Luminescence acetoacetic acid europium gadolinium lanthanide article chemical structure crystal structure ligand binding luminescence solid state X ray analysis |
| description |
Three new lanthanide oxydiacetate compounds have been prepared and their structures determined by single crystal X-ray methods: {[Ln2(oda)3(H2O)2]·5H2O}(n) (Ln = Eu, Gd) and [Eu(oda)(Hoda)(H2O)]·2H2O. The former are orthorhombic and Ama2, with LnO8 and LnO9 cores bridged by anti-anti carboxylate ligands and the latter is mononuclear containing a EuO9 core. Luminescence spectra of the europium complexes in the solid state are presented. (C) 2000 Elsevier Science S.A. |
| title |
Novel europium and gadolinium compounds in the lanthanide(III) oxydiacetate series |
| title_short |
Novel europium and gadolinium compounds in the lanthanide(III) oxydiacetate series |
| title_full |
Novel europium and gadolinium compounds in the lanthanide(III) oxydiacetate series |
| title_fullStr |
Novel europium and gadolinium compounds in the lanthanide(III) oxydiacetate series |
| title_full_unstemmed |
Novel europium and gadolinium compounds in the lanthanide(III) oxydiacetate series |
| title_sort |
novel europium and gadolinium compounds in the lanthanide(iii) oxydiacetate series |
| publishDate |
2000 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v303_n2_p306_Aramendia http://hdl.handle.net/20.500.12110/paper_00201693_v303_n2_p306_Aramendia |
| _version_ |
1768545538086535168 |