A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)

The dinuclear copper(II) complex [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate; phen=1,10-phenanthroline) has been prepared and characterized by single crystal X-ray diffraction. The dimer shows a strictly planar CuO2Cu ring involving monoatomic O-carboxylates in the bridging mode with each copper wea...

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Guardado en:
Detalles Bibliográficos
Publicado: 1999
Materias:
Carboxylate complexes
Copper complexes
Crystal structures
Dinuclear complexes
Thioether complexes
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v286_n1_p74_Baggio
http://hdl.handle.net/20.500.12110/paper_00201693_v286_n1_p74_Baggio
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_00201693_v286_n1_p74_Baggio
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spelling paper:paper_00201693_v286_n1_p74_Baggio2023-06-08T14:40:48Z A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline) Carboxylate complexes Copper complexes Crystal structures Dinuclear complexes Thioether complexes The dinuclear copper(II) complex [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate; phen=1,10-phenanthroline) has been prepared and characterized by single crystal X-ray diffraction. The dimer shows a strictly planar CuO2Cu ring involving monoatomic O-carboxylates in the bridging mode with each copper weakly bonded to a thioether in a distorted octahedral N2O3S environment. Variable temperature susceptibility measurements reveal the existence of weak ferromagnetic interactions within the dimer, mediated by the oxygen atoms of the bridge. © 1999 Elsevier Science S.A. 1999 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v286_n1_p74_Baggio http://hdl.handle.net/20.500.12110/paper_00201693_v286_n1_p74_Baggio
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Carboxylate complexes
Copper complexes
Crystal structures
Dinuclear complexes
Thioether complexes
spellingShingle Carboxylate complexes
Copper complexes
Crystal structures
Dinuclear complexes
Thioether complexes
A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)
topic_facet Carboxylate complexes
Copper complexes
Crystal structures
Dinuclear complexes
Thioether complexes
description The dinuclear copper(II) complex [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate; phen=1,10-phenanthroline) has been prepared and characterized by single crystal X-ray diffraction. The dimer shows a strictly planar CuO2Cu ring involving monoatomic O-carboxylates in the bridging mode with each copper weakly bonded to a thioether in a distorted octahedral N2O3S environment. Variable temperature susceptibility measurements reveal the existence of weak ferromagnetic interactions within the dimer, mediated by the oxygen atoms of the bridge. © 1999 Elsevier Science S.A.
title A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)
title_short A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)
title_full A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)
title_fullStr A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)
title_full_unstemmed A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)
title_sort dinuclear copper(ii) complex involving monoatomic o-carboxylate bridging and cu-s(thioether) bonds: [cu(tda)(phen)]2 · h2tda (tda=thiodiacetate, phen=phenanthroline)
publishDate 1999
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v286_n1_p74_Baggio
http://hdl.handle.net/20.500.12110/paper_00201693_v286_n1_p74_Baggio
_version_ 1768542770350260224

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