Adduct formation between zinc and cadmium oxydiacetates and imidazol. Crystal structures of [Zn(Him)2(oda)]n and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (Him=imidazol, oda=oxydiacetate)

The two new compounds [Zn(Him)2(oda)]n (1) and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (2) (Him=imidazol, oda=oxydiacetate) have been prepared and their structures determined by single-crystal X-ray diffraction studies. Compound 1 consists of polymeric chains formed by ZnN2O2 tetrahedral units bridged by the...

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Detalles Bibliográficos
Publicado: 1999
Materias:
Cadmium complexes
Crystal structures
Oxydiacetate complexes
Zinc complexes
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v284_n1_p49_Baggio
http://hdl.handle.net/20.500.12110/paper_00201693_v284_n1_p49_Baggio
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling paper:paper_00201693_v284_n1_p49_Baggio2023-06-08T14:40:48Z Adduct formation between zinc and cadmium oxydiacetates and imidazol. Crystal structures of [Zn(Him)2(oda)]n and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (Him=imidazol, oda=oxydiacetate) Cadmium complexes Crystal structures Oxydiacetate complexes Zinc complexes The two new compounds [Zn(Him)2(oda)]n (1) and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (2) (Him=imidazol, oda=oxydiacetate) have been prepared and their structures determined by single-crystal X-ray diffraction studies. Compound 1 consists of polymeric chains formed by ZnN2O2 tetrahedral units bridged by the carboxylate groups of extended oda ligands; 2 is tetranuclear with the cadmium atoms in pentagonal bipyramidal CdN2O5 coordination geometry. The extended structures and the hydrogen-bonding patterns displayed by both the compounds were examined. 1999 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v284_n1_p49_Baggio http://hdl.handle.net/20.500.12110/paper_00201693_v284_n1_p49_Baggio
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Cadmium complexes
Crystal structures
Oxydiacetate complexes
Zinc complexes
spellingShingle Cadmium complexes
Crystal structures
Oxydiacetate complexes
Zinc complexes
Adduct formation between zinc and cadmium oxydiacetates and imidazol. Crystal structures of [Zn(Him)2(oda)]n and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (Him=imidazol, oda=oxydiacetate)
topic_facet Cadmium complexes
Crystal structures
Oxydiacetate complexes
Zinc complexes
description The two new compounds [Zn(Him)2(oda)]n (1) and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (2) (Him=imidazol, oda=oxydiacetate) have been prepared and their structures determined by single-crystal X-ray diffraction studies. Compound 1 consists of polymeric chains formed by ZnN2O2 tetrahedral units bridged by the carboxylate groups of extended oda ligands; 2 is tetranuclear with the cadmium atoms in pentagonal bipyramidal CdN2O5 coordination geometry. The extended structures and the hydrogen-bonding patterns displayed by both the compounds were examined.
title Adduct formation between zinc and cadmium oxydiacetates and imidazol. Crystal structures of [Zn(Him)2(oda)]n and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (Him=imidazol, oda=oxydiacetate)
title_short Adduct formation between zinc and cadmium oxydiacetates and imidazol. Crystal structures of [Zn(Him)2(oda)]n and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (Him=imidazol, oda=oxydiacetate)
title_full Adduct formation between zinc and cadmium oxydiacetates and imidazol. Crystal structures of [Zn(Him)2(oda)]n and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (Him=imidazol, oda=oxydiacetate)
title_fullStr Adduct formation between zinc and cadmium oxydiacetates and imidazol. Crystal structures of [Zn(Him)2(oda)]n and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (Him=imidazol, oda=oxydiacetate)
title_full_unstemmed Adduct formation between zinc and cadmium oxydiacetates and imidazol. Crystal structures of [Zn(Him)2(oda)]n and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (Him=imidazol, oda=oxydiacetate)
title_sort adduct formation between zinc and cadmium oxydiacetates and imidazol. crystal structures of [zn(him)2(oda)]n and [cd2(him)4(oda)2(h2o)] 2·6h2o (him=imidazol, oda=oxydiacetate)
publishDate 1999
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v284_n1_p49_Baggio
http://hdl.handle.net/20.500.12110/paper_00201693_v284_n1_p49_Baggio
_version_ 1768542488527634432

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