Isolation and characterization of a polymeric lanthanum citrate

The first lanthanide citrate coordination polymer with the formula [La(Hcit)(H2O)]n (Hcit3- = C(OH)(COO -)(CH2COO-)2) was prepared from La2O3 and citric acid at pH = 2.2-2.5 under hydrothermal conditions at 120 °C. The compound was characterized by elemental analysis, IR, TG-DTA, and X-ray crystallo...

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Detalles Bibliográficos
Autor principal: Perec, Mireille
Publicado: 2004
Materias:
coordination compound
lanthanum
lanthanum citrate
unclassified drug
article
chemical analysis
crystallization
infrared spectroscopy
thermogravimetry
thermostability
X ray crystallography
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201669_v43_n22_p6965_Baggio
http://hdl.handle.net/20.500.12110/paper_00201669_v43_n22_p6965_Baggio
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_00201669_v43_n22_p6965_Baggio
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spelling paper:paper_00201669_v43_n22_p6965_Baggio2023-06-08T14:40:32Z Isolation and characterization of a polymeric lanthanum citrate Perec, Mireille coordination compound lanthanum lanthanum citrate unclassified drug article chemical analysis crystallization infrared spectroscopy thermogravimetry thermostability X ray crystallography The first lanthanide citrate coordination polymer with the formula [La(Hcit)(H2O)]n (Hcit3- = C(OH)(COO -)(CH2COO-)2) was prepared from La2O3 and citric acid at pH = 2.2-2.5 under hydrothermal conditions at 120 °C. The compound was characterized by elemental analysis, IR, TG-DTA, and X-ray crystallography. It is thermally stable up to 158 °C and insoluble in common solvents. The compound crystallizes in the monoclinic space group C2/c with a = 16.765(3) Å, b = 8.822(2) Å, c = 14.048(3) Å, β = 120.64(3)°, and Z = 8. The structure consists of chains of La(III) cations bridged by O-C-O groups with pendant Hcit anions forming a pillar structure. The Hcit ligand is involved in six La-O bonds to five different La centers in a very compact 3D structure. Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2004 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201669_v43_n22_p6965_Baggio http://hdl.handle.net/20.500.12110/paper_00201669_v43_n22_p6965_Baggio
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic coordination compound
lanthanum
lanthanum citrate
unclassified drug
article
chemical analysis
crystallization
infrared spectroscopy
thermogravimetry
thermostability
X ray crystallography
spellingShingle coordination compound
lanthanum
lanthanum citrate
unclassified drug
article
chemical analysis
crystallization
infrared spectroscopy
thermogravimetry
thermostability
X ray crystallography
Perec, Mireille
Isolation and characterization of a polymeric lanthanum citrate
topic_facet coordination compound
lanthanum
lanthanum citrate
unclassified drug
article
chemical analysis
crystallization
infrared spectroscopy
thermogravimetry
thermostability
X ray crystallography
description The first lanthanide citrate coordination polymer with the formula [La(Hcit)(H2O)]n (Hcit3- = C(OH)(COO -)(CH2COO-)2) was prepared from La2O3 and citric acid at pH = 2.2-2.5 under hydrothermal conditions at 120 °C. The compound was characterized by elemental analysis, IR, TG-DTA, and X-ray crystallography. It is thermally stable up to 158 °C and insoluble in common solvents. The compound crystallizes in the monoclinic space group C2/c with a = 16.765(3) Å, b = 8.822(2) Å, c = 14.048(3) Å, β = 120.64(3)°, and Z = 8. The structure consists of chains of La(III) cations bridged by O-C-O groups with pendant Hcit anions forming a pillar structure. The Hcit ligand is involved in six La-O bonds to five different La centers in a very compact 3D structure.
author Perec, Mireille
author_facet Perec, Mireille
author_sort Perec, Mireille
title Isolation and characterization of a polymeric lanthanum citrate
title_short Isolation and characterization of a polymeric lanthanum citrate
title_full Isolation and characterization of a polymeric lanthanum citrate
title_fullStr Isolation and characterization of a polymeric lanthanum citrate
title_full_unstemmed Isolation and characterization of a polymeric lanthanum citrate
title_sort isolation and characterization of a polymeric lanthanum citrate
publishDate 2004
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201669_v43_n22_p6965_Baggio
http://hdl.handle.net/20.500.12110/paper_00201669_v43_n22_p6965_Baggio
work_keys_str_mv AT perecmireille isolationandcharacterizationofapolymericlanthanumcitrate
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