Synthetically useful metal-mediated radical transformations in water and aqueous media

In this review non-carbon-centered radicals are used in water and aqueous mixtures to induce and accomplish several synthetically useful organic transformations such as Reformatsky reactions, alkylation and allylation reactions of carbonyl compounds, electron deficient alkenes and imine derivatives,...

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Detalles Bibliográficos
Publicado: 2011
Materias:
Metal radicals in water
Metal-mediated radical alkylation and allylation reactions in water
Metal-mediated radical cyclizations in water
Metal-mediated radical reductions and oxidations in water
Metal-mediated reductive cross coupling in water
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00108545_v255_n23-24_p2991_Postigo
http://hdl.handle.net/20.500.12110/paper_00108545_v255_n23-24_p2991_Postigo
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_00108545_v255_n23-24_p2991_Postigo
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spelling paper:paper_00108545_v255_n23-24_p2991_Postigo2023-06-08T14:34:42Z Synthetically useful metal-mediated radical transformations in water and aqueous media Metal radicals in water Metal-mediated radical alkylation and allylation reactions in water Metal-mediated radical cyclizations in water Metal-mediated radical reductions and oxidations in water Metal-mediated reductive cross coupling in water In this review non-carbon-centered radicals are used in water and aqueous mixtures to induce and accomplish several synthetically useful organic transformations such as Reformatsky reactions, alkylation and allylation reactions of carbonyl compounds, electron deficient alkenes and imine derivatives, radical conjugate additions, metal-mediated radical cyclizations, reductive cross coupling reactions and other coupling reactions, oxidation and reduction reactions in water. In doing so, the array of metal radicals used encompass elements from the main groups (IIIB, IVB, VB and VIB groups), as well as transition metals. However, the important class of radical hydrometallation reactions of carbon-carbon multiple bonds in water is not the subject of this work. © 2011 Elsevier B.V. 2011 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00108545_v255_n23-24_p2991_Postigo http://hdl.handle.net/20.500.12110/paper_00108545_v255_n23-24_p2991_Postigo
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Metal radicals in water
Metal-mediated radical alkylation and allylation reactions in water
Metal-mediated radical cyclizations in water
Metal-mediated radical reductions and oxidations in water
Metal-mediated reductive cross coupling in water
spellingShingle Metal radicals in water
Metal-mediated radical alkylation and allylation reactions in water
Metal-mediated radical cyclizations in water
Metal-mediated radical reductions and oxidations in water
Metal-mediated reductive cross coupling in water
Synthetically useful metal-mediated radical transformations in water and aqueous media
topic_facet Metal radicals in water
Metal-mediated radical alkylation and allylation reactions in water
Metal-mediated radical cyclizations in water
Metal-mediated radical reductions and oxidations in water
Metal-mediated reductive cross coupling in water
description In this review non-carbon-centered radicals are used in water and aqueous mixtures to induce and accomplish several synthetically useful organic transformations such as Reformatsky reactions, alkylation and allylation reactions of carbonyl compounds, electron deficient alkenes and imine derivatives, radical conjugate additions, metal-mediated radical cyclizations, reductive cross coupling reactions and other coupling reactions, oxidation and reduction reactions in water. In doing so, the array of metal radicals used encompass elements from the main groups (IIIB, IVB, VB and VIB groups), as well as transition metals. However, the important class of radical hydrometallation reactions of carbon-carbon multiple bonds in water is not the subject of this work. © 2011 Elsevier B.V.
title Synthetically useful metal-mediated radical transformations in water and aqueous media
title_short Synthetically useful metal-mediated radical transformations in water and aqueous media
title_full Synthetically useful metal-mediated radical transformations in water and aqueous media
title_fullStr Synthetically useful metal-mediated radical transformations in water and aqueous media
title_full_unstemmed Synthetically useful metal-mediated radical transformations in water and aqueous media
title_sort synthetically useful metal-mediated radical transformations in water and aqueous media
publishDate 2011
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00108545_v255_n23-24_p2991_Postigo
http://hdl.handle.net/20.500.12110/paper_00108545_v255_n23-24_p2991_Postigo
_version_ 1768543592376172544

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