Thermal effects on the electric deflection of toluene molecules

A series of precise electric deflection experiments were done on a supersonic beam of toluene molecules in several expansion conditions and field strengths. We analyzed the effect of a gradual rotational cooling on the evolution of the beam profile by use of the available theories of asymmetric-top...

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Autores principales:	Carrera, Alvaro, Moriena, Gustavo, Marceca, Ernesto Jose
Publicado:	2008
Materias:	Electric fields Fullerenes Toluene Beam profiles Electric deflections Field strengths Rotational cooling Rotational motions Supersonic beams Toluene molecules Thermal expansion
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00092614_v467_n1-3_p14_Carrera http://hdl.handle.net/20.500.12110/paper_00092614_v467_n1-3_p14_Carrera
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_00092614_v467_n1-3_p14_Carrera
record_format	dspace
spelling	paper:paper_00092614_v467_n1-3_p14_Carrera2023-06-08T14:33:52Z Thermal effects on the electric deflection of toluene molecules Carrera, Alvaro Moriena, Gustavo Marceca, Ernesto Jose Electric fields Fullerenes Toluene Beam profiles Electric deflections Field strengths Rotational cooling Rotational motions Supersonic beams Toluene molecules Thermal expansion A series of precise electric deflection experiments were done on a supersonic beam of toluene molecules in several expansion conditions and field strengths. We analyzed the effect of a gradual rotational cooling on the evolution of the beam profile by use of the available theories of asymmetric-top dipoles in electric fields. We have recorded from non-broadened (warm) to very broad and asymmetric (cold) profiles, and discussed this effect in terms of the Stark perturbation on the rotational motion. © 2008 Elsevier B.V. All rights reserved. Fil:Carrera, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Moriena, G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Marceca, E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2008 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00092614_v467_n1-3_p14_Carrera http://hdl.handle.net/20.500.12110/paper_00092614_v467_n1-3_p14_Carrera
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Electric fields Fullerenes Toluene Beam profiles Electric deflections Field strengths Rotational cooling Rotational motions Supersonic beams Toluene molecules Thermal expansion
spellingShingle	Electric fields Fullerenes Toluene Beam profiles Electric deflections Field strengths Rotational cooling Rotational motions Supersonic beams Toluene molecules Thermal expansion Carrera, Alvaro Moriena, Gustavo Marceca, Ernesto Jose Thermal effects on the electric deflection of toluene molecules
topic_facet	Electric fields Fullerenes Toluene Beam profiles Electric deflections Field strengths Rotational cooling Rotational motions Supersonic beams Toluene molecules Thermal expansion
description	A series of precise electric deflection experiments were done on a supersonic beam of toluene molecules in several expansion conditions and field strengths. We analyzed the effect of a gradual rotational cooling on the evolution of the beam profile by use of the available theories of asymmetric-top dipoles in electric fields. We have recorded from non-broadened (warm) to very broad and asymmetric (cold) profiles, and discussed this effect in terms of the Stark perturbation on the rotational motion. © 2008 Elsevier B.V. All rights reserved.
author	Carrera, Alvaro Moriena, Gustavo Marceca, Ernesto Jose
author_facet	Carrera, Alvaro Moriena, Gustavo Marceca, Ernesto Jose
author_sort	Carrera, Alvaro
title	Thermal effects on the electric deflection of toluene molecules
title_short	Thermal effects on the electric deflection of toluene molecules
title_full	Thermal effects on the electric deflection of toluene molecules
title_fullStr	Thermal effects on the electric deflection of toluene molecules
title_full_unstemmed	Thermal effects on the electric deflection of toluene molecules
title_sort	thermal effects on the electric deflection of toluene molecules
publishDate	2008
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00092614_v467_n1-3_p14_Carrera http://hdl.handle.net/20.500.12110/paper_00092614_v467_n1-3_p14_Carrera
work_keys_str_mv	AT carreraalvaro thermaleffectsontheelectricdeflectionoftoluenemolecules AT morienagustavo thermaleffectsontheelectricdeflectionoftoluenemolecules AT marcecaernestojose thermaleffectsontheelectricdeflectionoftoluenemolecules
_version_	1768542918422822912

Thermal effects on the electric deflection of toluene molecules

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