Hydrogen storage on a novel nanostructured carbón material modified with zirconia
In this work, we report the synthesis and characterization of zirconium oxide supported in nanostructured carbon material synthesized by a new direct synthesis technique. The goal of this new method is to avoid the use of inorganic siliceous template (SBA-15), which leads to a shorter and cheaper...
| Autores principales: | , , , |
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| Formato: | Documento de conferencia publisherVersion |
| Lenguaje: | Inglés |
| Publicado: |
2022
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| Acceso en línea: | http://hdl.handle.net/20.500.12272/6601 |
| Aporte de: |
| id |
I68-R174-20.500.12272-6601 |
|---|---|
| record_format |
dspace |
| institution |
Universidad Tecnológica Nacional |
| institution_str |
I-68 |
| repository_str |
R-174 |
| collection |
RIA - Repositorio Institucional Abierto (UTN) |
| language |
Inglés |
| topic |
CMK-3 HYDROGEN STORAGE ZIRCONIA |
| spellingShingle |
CMK-3 HYDROGEN STORAGE ZIRCONIA Juárez, Juliana M. Gómez Costa, Marcos B. Anunziata, Oscar A. Venosta, Lisandro F. Hydrogen storage on a novel nanostructured carbón material modified with zirconia |
| topic_facet |
CMK-3 HYDROGEN STORAGE ZIRCONIA |
| description |
In this work, we report the synthesis and characterization of zirconium oxide supported in
nanostructured carbon material synthesized by a new direct synthesis technique.
The goal of this new method is to avoid the use of inorganic siliceous template (SBA-15), which
leads to a shorter and cheaper way to obtain mesoporous carbon, and at the same time
incorporate into the framework Zirconium atoms.
The material with zirconium oxide (Zr-CMK-3) was successfully synthesized and characterized by Xray
diffraction, SEM, RAMAN and textural properties, UV-Vis-DRS, X-ray photoelectron
spectroscopy and transmission electron microscopy analyses.
Zr-CMK-3 improved significantly the H2 storage behavior (4.6 wt% at 77 K and 10 bar) compared
with CMK-3. The synthesized material is promising for hydrogen uptake by means of weak
bonding (physisorption).
The activity of the samples to the adsorption of hydrogen molecules is attributed to the improved
dispersion of the zirconium oxide, as well as the appropriate use of support, which can probably
disperse the zirconium on its large surface area, allowing a great dispersion of the zirconium.
The Zr+4 cation is an active species to absorb and store hydrogen through a physisorption process
and the carbon plays an important role in the dispersion and size of metal particles.
A hydrogen storage mechanism on the active surface of the ZrO2 clusters was proposed. First layer
of hydrogen molecules can react with the metal cation through a dihydrogen complex (Kubas
interaction). The second layer of hydrogen molecules adsorbed around the metal oxide clusters is
due to dipole-like interactions, this is because the metal particle induces dipole forces on the
hydrogen molecule. The other layers could also interact by dipole forces; however, the interaction
force decreases as the distance to the surface increases. The upper layers could interact with the
metal cation by dipole-induced bonding; however, the interaction force decreases as the distance to
the surface increases. |
| format |
Documento de conferencia publisherVersion |
| author |
Juárez, Juliana M. Gómez Costa, Marcos B. Anunziata, Oscar A. Venosta, Lisandro F. |
| author_facet |
Juárez, Juliana M. Gómez Costa, Marcos B. Anunziata, Oscar A. Venosta, Lisandro F. |
| author_sort |
Juárez, Juliana M. |
| title |
Hydrogen storage on a novel nanostructured carbón material modified with zirconia |
| title_short |
Hydrogen storage on a novel nanostructured carbón material modified with zirconia |
| title_full |
Hydrogen storage on a novel nanostructured carbón material modified with zirconia |
| title_fullStr |
Hydrogen storage on a novel nanostructured carbón material modified with zirconia |
| title_full_unstemmed |
Hydrogen storage on a novel nanostructured carbón material modified with zirconia |
| title_sort |
hydrogen storage on a novel nanostructured carbón material modified with zirconia |
| publishDate |
2022 |
| url |
http://hdl.handle.net/20.500.12272/6601 |
| work_keys_str_mv |
AT juarezjulianam hydrogenstorageonanovelnanostructuredcarbonmaterialmodifiedwithzirconia AT gomezcostamarcosb hydrogenstorageonanovelnanostructuredcarbonmaterialmodifiedwithzirconia AT anunziataoscara hydrogenstorageonanovelnanostructuredcarbonmaterialmodifiedwithzirconia AT venostalisandrof hydrogenstorageonanovelnanostructuredcarbonmaterialmodifiedwithzirconia |
| bdutipo_str |
Repositorios |
| _version_ |
1764820553060843522 |