Design and synthesis of the new bis-vainilline derivatives containing hydralazine and isoniazide moieties for the detection of trivalent metal cations
In the present work the design and synthesis of new chemosensors for the determination of metal cations represent an area of hight interest in supramolecular chemistry. The detection and cuantification is important in many fields of application such as environmental bioinorganic chemistry, develop...
Autores principales: | , , , |
---|---|
Formato: | Documento de conferencia publishedVersion |
Lenguaje: | Inglés Inglés |
Publicado: |
2019
|
Materias: | |
Acceso en línea: | http://hdl.handle.net/20.500.12272/4085 |
Aporte de: |
id |
I68-R174-20.500.12272-4085 |
---|---|
record_format |
dspace |
institution |
Universidad Tecnológica Nacional |
institution_str |
I-68 |
repository_str |
R-174 |
collection |
RIA - Repositorio Institucional Abierto (UTN) |
language |
Inglés Inglés |
topic |
chemosensor composite Cu2+ ion |
spellingShingle |
chemosensor composite Cu2+ ion Quindt, M. Guntero, Vanina A. Mancini, Pedro M. E. Kneeteman, María N. Design and synthesis of the new bis-vainilline derivatives containing hydralazine and isoniazide moieties for the detection of trivalent metal cations |
topic_facet |
chemosensor composite Cu2+ ion |
description |
In the present work the design and synthesis of new chemosensors for the determination of metal cations
represent an area of hight interest in supramolecular chemistry. The detection and cuantification is important in many fields of application such as environmental bioinorganic
chemistry, developmental biology, clinical toxicology, waste management, and bioremediation of radionuclides and metal ions[1]. Besides, there is a growing concern for determining trivalent metal cations as Fe3+, Cr3+ and Al3+ which are highly toxic. Classic chemosensors for Cr3+ and Fe3+ interfere between them, consequently, the development of systems that allow selective and sensitive detection is desirable.
It is known that derivatives of bis-vainilline that contain semicarbazide or hydrazines can act as sensors of cations. In that direction two new probes were developed from bis-vainilline
condensed in positions 3- and 3’- with hydrazoline and isoniazide, using fluorescence as analytical signal for detection of analytes, because fluorimetry is rapidly performed, nondestructive and highly sensitive. |
format |
Documento de conferencia publishedVersion Documento de conferencia |
author |
Quindt, M. Guntero, Vanina A. Mancini, Pedro M. E. Kneeteman, María N. |
author_facet |
Quindt, M. Guntero, Vanina A. Mancini, Pedro M. E. Kneeteman, María N. |
author_sort |
Quindt, M. |
title |
Design and synthesis of the new bis-vainilline derivatives containing hydralazine and isoniazide moieties for the detection of trivalent metal cations |
title_short |
Design and synthesis of the new bis-vainilline derivatives containing hydralazine and isoniazide moieties for the detection of trivalent metal cations |
title_full |
Design and synthesis of the new bis-vainilline derivatives containing hydralazine and isoniazide moieties for the detection of trivalent metal cations |
title_fullStr |
Design and synthesis of the new bis-vainilline derivatives containing hydralazine and isoniazide moieties for the detection of trivalent metal cations |
title_full_unstemmed |
Design and synthesis of the new bis-vainilline derivatives containing hydralazine and isoniazide moieties for the detection of trivalent metal cations |
title_sort |
design and synthesis of the new bis-vainilline derivatives containing hydralazine and isoniazide moieties for the detection of trivalent metal cations |
publishDate |
2019 |
url |
http://hdl.handle.net/20.500.12272/4085 |
work_keys_str_mv |
AT quindtm designandsynthesisofthenewbisvainillinederivativescontaininghydralazineandisoniazidemoietiesforthedetectionoftrivalentmetalcations AT gunterovaninaa designandsynthesisofthenewbisvainillinederivativescontaininghydralazineandisoniazidemoietiesforthedetectionoftrivalentmetalcations AT mancinipedrome designandsynthesisofthenewbisvainillinederivativescontaininghydralazineandisoniazidemoietiesforthedetectionoftrivalentmetalcations AT kneetemanmarian designandsynthesisofthenewbisvainillinederivativescontaininghydralazineandisoniazidemoietiesforthedetectionoftrivalentmetalcations |
bdutipo_str |
Repositorios |
_version_ |
1764820551351664640 |