Brown rice authenticity evaluation by spark discharge-laser-induced breakdown spectroscopy
Rice is the most consumed food worldwide, therefore its designation of origin (PDO) is very useful. Laserinduced breakdown spectroscopy (LIBS) is an interesting analytical technique for PDO certification, since it provides fast multielemental analysis requiring minimal sample treatment. In this work...
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Autores principales: | , , , , , , |
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Formato: | Artículo |
Lenguaje: | Inglés |
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Elsevier
2021
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Materias: | |
Acceso en línea: | http://repositorio.unne.edu.ar/handle/123456789/27982 |
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I48-R184-123456789-27982 |
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institution |
Universidad Nacional del Nordeste |
institution_str |
I-48 |
repository_str |
R-184 |
collection |
RIUNNE - Repositorio Institucional de la Universidad Nacional del Nordeste (UNNE) |
language |
Inglés |
topic |
Food authenticity Pdo Brown rice Sd-Libs Pattern recognition |
spellingShingle |
Food authenticity Pdo Brown rice Sd-Libs Pattern recognition Pérez Rodríguez, Michael Dirchwolf, Pamela Maia Silva, Tiago Varão Villafañe, Roxana Noelia Gómez Neto, José Anchieta Pellerano, Roberto Gerardo Ferreira, Edilene Cristina Brown rice authenticity evaluation by spark discharge-laser-induced breakdown spectroscopy |
topic_facet |
Food authenticity Pdo Brown rice Sd-Libs Pattern recognition |
description |
Rice is the most consumed food worldwide, therefore its designation of origin (PDO) is very useful. Laserinduced breakdown spectroscopy (LIBS) is an interesting analytical technique for PDO certification, since it provides fast multielemental analysis requiring minimal sample treatment. In this work LIBS spectral data from rice analysis were evaluated for PDO certification of Argentine brown rice. Samples from two PDOs were analyzed by LIBS coupled to spark discharge. The selection of spectral data was accomplished by extreme gradient boosting (XGBoost), an algorithm currently used in machine learning, but rarely applied in chemical issues. Emission lines of C, Ca, Fe, Mg and Na were selected, and the best performance of classification were obtained using k-nearest neighbor (k-NN) algorithm. The developed method provided 84% of accuracy, 100% of sensitivity and 78% of specificity in classification of test samples. Furthermore, it is simple, clean and can be easily applied for rice certification. |
format |
Artículo |
author |
Pérez Rodríguez, Michael Dirchwolf, Pamela Maia Silva, Tiago Varão Villafañe, Roxana Noelia Gómez Neto, José Anchieta Pellerano, Roberto Gerardo Ferreira, Edilene Cristina |
author_facet |
Pérez Rodríguez, Michael Dirchwolf, Pamela Maia Silva, Tiago Varão Villafañe, Roxana Noelia Gómez Neto, José Anchieta Pellerano, Roberto Gerardo Ferreira, Edilene Cristina |
author_sort |
Pérez Rodríguez, Michael |
title |
Brown rice authenticity evaluation by spark discharge-laser-induced breakdown spectroscopy |
title_short |
Brown rice authenticity evaluation by spark discharge-laser-induced breakdown spectroscopy |
title_full |
Brown rice authenticity evaluation by spark discharge-laser-induced breakdown spectroscopy |
title_fullStr |
Brown rice authenticity evaluation by spark discharge-laser-induced breakdown spectroscopy |
title_full_unstemmed |
Brown rice authenticity evaluation by spark discharge-laser-induced breakdown spectroscopy |
title_sort |
brown rice authenticity evaluation by spark discharge-laser-induced breakdown spectroscopy |
publisher |
Elsevier |
publishDate |
2021 |
url |
http://repositorio.unne.edu.ar/handle/123456789/27982 |
work_keys_str_mv |
AT perezrodriguezmichael brownriceauthenticityevaluationbysparkdischargelaserinducedbreakdownspectroscopy AT dirchwolfpamelamaia brownriceauthenticityevaluationbysparkdischargelaserinducedbreakdownspectroscopy AT silvatiagovarao brownriceauthenticityevaluationbysparkdischargelaserinducedbreakdownspectroscopy AT villafaneroxananoelia brownriceauthenticityevaluationbysparkdischargelaserinducedbreakdownspectroscopy AT gomeznetojoseanchieta brownriceauthenticityevaluationbysparkdischargelaserinducedbreakdownspectroscopy AT pelleranorobertogerardo brownriceauthenticityevaluationbysparkdischargelaserinducedbreakdownspectroscopy AT ferreiraedilenecristina brownriceauthenticityevaluationbysparkdischargelaserinducedbreakdownspectroscopy |
bdutipo_str |
Repositorios |
_version_ |
1764820539007827974 |