Organic Synthesis in Water Mediated By Silyl Radicals

This account is focused on highlighting the recent advances on synthetically-useful organic reactions employing siliconcentered radicals in water, and presenting new reactions in water, mediated by silyl radicals. In doing so, several types of organic radical transformations will be discussed, such...

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Detalles Bibliográficos
Autores principales:	Barata-Vallejo, Sebastian, Sbarbati Nudelman, Norma, Postigo, Al
Formato:	Artículo
Lenguaje:	Inglés
Publicado:	Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación 2014
Materias:	silyl radicals in water radical carbon-carbon bond formation in water chain carrier portador de la cadena formación de enlaces carbono-carbono radical en agua radicales sililo en el agua
Acceso en línea:	http://repositorio.ub.edu.ar/handle/123456789/2722
Aporte de:	Repositorio Institucional - Universidad de Belgrano (UB) de Universidad de Belgrano

id	I36-R142-123456789-2722
record_format	dspace
institution	Universidad de Belgrano
institution_str	I-36
repository_str	R-142
collection	Repositorio Institucional - Universidad de Belgrano (UB)
language	Inglés
topic	silyl radicals in water radical carbon-carbon bond formation in water chain carrier portador de la cadena formación de enlaces carbono-carbono radical en agua radicales sililo en el agua
spellingShingle	silyl radicals in water radical carbon-carbon bond formation in water chain carrier portador de la cadena formación de enlaces carbono-carbono radical en agua radicales sililo en el agua Barata-Vallejo, Sebastian Sbarbati Nudelman, Norma Postigo, Al Organic Synthesis in Water Mediated By Silyl Radicals
topic_facet	silyl radicals in water radical carbon-carbon bond formation in water chain carrier portador de la cadena formación de enlaces carbono-carbono radical en agua radicales sililo en el agua
description	This account is focused on highlighting the recent advances on synthetically-useful organic reactions employing siliconcentered radicals in water, and presenting new reactions in water, mediated by silyl radicals. In doing so, several types of organic radical transformations will be discussed, such as reduction of organic halides utilizing non toxic organosilane reducing agents in water, transformation of azides into amines, synthesis of protecting silyl ethers in water, hydrosilylation reactions of carbon-carbon double and triple bonds, and radical cyclization reactions in water induced by silicon-centered radicals. More recently, intermolecular radical carboncarbon bond formation reactions mediated by silyl radicals have allowed the synthesis of perfluoroalkyl-substituted compounds in water, widening the scope for the syntheses of fluorophoes.
format	Article
author	Barata-Vallejo, Sebastian Sbarbati Nudelman, Norma Postigo, Al
author_facet	Barata-Vallejo, Sebastian Sbarbati Nudelman, Norma Postigo, Al
author_sort	Barata-Vallejo, Sebastian
title	Organic Synthesis in Water Mediated By Silyl Radicals
title_short	Organic Synthesis in Water Mediated By Silyl Radicals
title_full	Organic Synthesis in Water Mediated By Silyl Radicals
title_fullStr	Organic Synthesis in Water Mediated By Silyl Radicals
title_full_unstemmed	Organic Synthesis in Water Mediated By Silyl Radicals
title_sort	organic synthesis in water mediated by silyl radicals
publisher	Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación
publishDate	2014
url	http://repositorio.ub.edu.ar/handle/123456789/2722
work_keys_str_mv	AT baratavallejosebastian organicsynthesisinwatermediatedbysilylradicals AT sbarbatinudelmannorma organicsynthesisinwatermediatedbysilylradicals AT postigoal organicsynthesisinwatermediatedbysilylradicals
bdutipo_str	Repositorios
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Organic Synthesis in Water Mediated By Silyl Radicals

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