Behavior of thiosemicarbazones derived from some terpenones under acetylating conditions

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Preparation of chiral heterocyclic compounds of the thiadiazoline types, starting from natural terpenones such as fenchone, camphor and menthone, is described. Stereochemical assignment of the compounds synthesized was performed by NMR spectroscopy and X-ray analysis.

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Detalles Bibliográficos
Autores principales: Brousse, B.N., Moglioni, A.G., Alho, M.M., Álvarez-Larena, Á., Moltrasio, G.Y., D'Accorso, N.B.
Formato: Artículo publishedVersion
Publicado: 2002
Materias:
Asymmetric spiro-heterocyclic compounds
Terpenones
Thiadiazolines
Thiosemicarbazones
1,3,3 trimethyl 2 norcamphanone
camphor
heterocyclic compound
menthone
n [aza(1,7,7 trimethylbicyclo[2.2.1]hept 2 ylidene)methyl]acetamide
terpene derivative
thiadiazoline derivative
thiosemicarbazone derivative
unclassified drug
acetylation
article
carbohydrate synthesis
carbon nuclear magnetic resonance
chirality
proton nuclear magnetic resonance
stereochemistry
structure analysis
X ray diffraction
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_14246376_v2002_n10_p14_Brousse
https://repositoriouba.sisbi.uba.ar/gsdl/cgi-bin/library.cgi?a=d&c=artiaex&d=paper_14246376_v2002_n10_p14_Brousse_oai
Aporte de:
Repositorio Digital de la Universidad de Buenos Aires (UBA) de Universidad de Buenos Aires
Descripción
Sumario:Preparation of chiral heterocyclic compounds of the thiadiazoline types, starting from natural terpenones such as fenchone, camphor and menthone, is described. Stereochemical assignment of the compounds synthesized was performed by NMR spectroscopy and X-ray analysis.

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