Behavior of thiosemicarbazones derived from some terpenones under acetylating conditions

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Preparation of chiral heterocyclic compounds of the thiadiazoline types, starting from natural terpenones such as fenchone, camphor and menthone, is described. Stereochemical assignment of the compounds synthesized was performed by NMR spectroscopy and X-ray analysis.

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Autores principales: Brousse, B.N., Moglioni, A.G., Alho, M.M., Álvarez-Larena, Á., Moltrasio, G.Y., D'Accorso, N.B.
Formato: Artículo publishedVersion
Publicado: 2002
Materias:
Asymmetric spiro-heterocyclic compounds
Terpenones
Thiadiazolines
Thiosemicarbazones
1,3,3 trimethyl 2 norcamphanone
camphor
heterocyclic compound
menthone
n [aza(1,7,7 trimethylbicyclo[2.2.1]hept 2 ylidene)methyl]acetamide
terpene derivative
thiadiazoline derivative
thiosemicarbazone derivative
unclassified drug
acetylation
article
carbohydrate synthesis
carbon nuclear magnetic resonance
chirality
proton nuclear magnetic resonance
stereochemistry
structure analysis
X ray diffraction
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_14246376_v2002_n10_p14_Brousse
https://repositoriouba.sisbi.uba.ar/gsdl/cgi-bin/library.cgi?a=d&c=artiaex&d=paper_14246376_v2002_n10_p14_Brousse_oai
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Repositorio Digital de la Universidad de Buenos Aires (UBA) de Universidad de Buenos Aires
id I28-R145-paper_14246376_v2002_n10_p14_Brousse_oai
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spelling I28-R145-paper_14246376_v2002_n10_p14_Brousse_oai2024-08-16 Brousse, B.N. Moglioni, A.G. Alho, M.M. Álvarez-Larena, Á. Moltrasio, G.Y. D'Accorso, N.B. 2002 Preparation of chiral heterocyclic compounds of the thiadiazoline types, starting from natural terpenones such as fenchone, camphor and menthone, is described. Stereochemical assignment of the compounds synthesized was performed by NMR spectroscopy and X-ray analysis. Fil:Alho, M.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Moltrasio, G.Y. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:D'Accorso, N.B. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. application/pdf http://hdl.handle.net/20.500.12110/paper_14246376_v2002_n10_p14_Brousse info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar Arkivoc 2002;2002(10):14-23 Asymmetric spiro-heterocyclic compounds Terpenones Thiadiazolines Thiosemicarbazones 1,3,3 trimethyl 2 norcamphanone camphor heterocyclic compound menthone n [aza(1,7,7 trimethylbicyclo[2.2.1]hept 2 ylidene)methyl]acetamide terpene derivative thiadiazoline derivative thiosemicarbazone derivative unclassified drug acetylation article carbohydrate synthesis carbon nuclear magnetic resonance chirality proton nuclear magnetic resonance stereochemistry structure analysis X ray diffraction Behavior of thiosemicarbazones derived from some terpenones under acetylating conditions info:eu-repo/semantics/article info:ar-repo/semantics/artículo info:eu-repo/semantics/publishedVersion https://repositoriouba.sisbi.uba.ar/gsdl/cgi-bin/library.cgi?a=d&c=artiaex&d=paper_14246376_v2002_n10_p14_Brousse_oai
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-145
collection Repositorio Digital de la Universidad de Buenos Aires (UBA)
topic Asymmetric spiro-heterocyclic compounds
Terpenones
Thiadiazolines
Thiosemicarbazones
1,3,3 trimethyl 2 norcamphanone
camphor
heterocyclic compound
menthone
n [aza(1,7,7 trimethylbicyclo[2.2.1]hept 2 ylidene)methyl]acetamide
terpene derivative
thiadiazoline derivative
thiosemicarbazone derivative
unclassified drug
acetylation
article
carbohydrate synthesis
carbon nuclear magnetic resonance
chirality
proton nuclear magnetic resonance
stereochemistry
structure analysis
X ray diffraction
spellingShingle Asymmetric spiro-heterocyclic compounds
Terpenones
Thiadiazolines
Thiosemicarbazones
1,3,3 trimethyl 2 norcamphanone
camphor
heterocyclic compound
menthone
n [aza(1,7,7 trimethylbicyclo[2.2.1]hept 2 ylidene)methyl]acetamide
terpene derivative
thiadiazoline derivative
thiosemicarbazone derivative
unclassified drug
acetylation
article
carbohydrate synthesis
carbon nuclear magnetic resonance
chirality
proton nuclear magnetic resonance
stereochemistry
structure analysis
X ray diffraction
Brousse, B.N.
Moglioni, A.G.
Alho, M.M.
Álvarez-Larena, Á.
Moltrasio, G.Y.
D'Accorso, N.B.
Behavior of thiosemicarbazones derived from some terpenones under acetylating conditions
topic_facet Asymmetric spiro-heterocyclic compounds
Terpenones
Thiadiazolines
Thiosemicarbazones
1,3,3 trimethyl 2 norcamphanone
camphor
heterocyclic compound
menthone
n [aza(1,7,7 trimethylbicyclo[2.2.1]hept 2 ylidene)methyl]acetamide
terpene derivative
thiadiazoline derivative
thiosemicarbazone derivative
unclassified drug
acetylation
article
carbohydrate synthesis
carbon nuclear magnetic resonance
chirality
proton nuclear magnetic resonance
stereochemistry
structure analysis
X ray diffraction
description Preparation of chiral heterocyclic compounds of the thiadiazoline types, starting from natural terpenones such as fenchone, camphor and menthone, is described. Stereochemical assignment of the compounds synthesized was performed by NMR spectroscopy and X-ray analysis.
format Artículo
Artículo
publishedVersion
author Brousse, B.N.
Moglioni, A.G.
Alho, M.M.
Álvarez-Larena, Á.
Moltrasio, G.Y.
D'Accorso, N.B.
author_facet Brousse, B.N.
Moglioni, A.G.
Alho, M.M.
Álvarez-Larena, Á.
Moltrasio, G.Y.
D'Accorso, N.B.
author_sort Brousse, B.N.
title Behavior of thiosemicarbazones derived from some terpenones under acetylating conditions
title_short Behavior of thiosemicarbazones derived from some terpenones under acetylating conditions
title_full Behavior of thiosemicarbazones derived from some terpenones under acetylating conditions
title_fullStr Behavior of thiosemicarbazones derived from some terpenones under acetylating conditions
title_full_unstemmed Behavior of thiosemicarbazones derived from some terpenones under acetylating conditions
title_sort behavior of thiosemicarbazones derived from some terpenones under acetylating conditions
publishDate 2002
url http://hdl.handle.net/20.500.12110/paper_14246376_v2002_n10_p14_Brousse
https://repositoriouba.sisbi.uba.ar/gsdl/cgi-bin/library.cgi?a=d&c=artiaex&d=paper_14246376_v2002_n10_p14_Brousse_oai
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