First synthesis of (20S) 3β,16β-dihydroxy-5-pregnen-20,16- carbolactone (diosgeninlactone)

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Diosgeninlactone (1), a natural product from Solanum vespertilio, was stereo-selectively synthesized in high yield from 3β-hydroxy-5-androstene.

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Detalles Bibliográficos
Autores principales:	Bruttomesso, A.C., Gros, E.G.
Formato:	Artículo publishedVersion
Publicado:	2000
Materias:	(20) 3beta,16beta dihydroxy 5 pregnen 20,16 carbolactone 3beta hydroxy 5 androsterone alkaloid derivative androsterone diosgenin hydroxyl group lactone sapogenin steroid unclassified drug catabolism cis isomer conference paper correlation analysis extraction fruit molecular dynamics molecular interaction molecular mechanics plant plant yield probability protein degradation protein isolation solanum vespertilio stereochemistry synthesis technique tomato vegetable
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_14203049_v5_n3_p564_Bruttomesso https://repositoriouba.sisbi.uba.ar/gsdl/cgi-bin/library.cgi?a=d&c=artiaex&d=paper_14203049_v5_n3_p564_Bruttomesso_oai
Aporte de:	Repositorio Digital de la Universidad de Buenos Aires (UBA) de Universidad de Buenos Aires

Descripción
Sumario:	Diosgeninlactone (1), a natural product from Solanum vespertilio, was stereo-selectively synthesized in high yield from 3β-hydroxy-5-androstene.