First synthesis of (20S) 3β,16β-dihydroxy-5-pregnen-20,16- carbolactone (diosgeninlactone)
Diosgeninlactone (1), a natural product from Solanum vespertilio, was stereo-selectively synthesized in high yield from 3β-hydroxy-5-androstene.
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2000
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_14203049_v5_n3_p564_Bruttomesso http://repositoriouba.sisbi.uba.ar/gsdl/cgi-bin/library.cgi?a=d&c=artiaex&d=paper_14203049_v5_n3_p564_Bruttomesso_oai |
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I28-R145-paper_14203049_v5_n3_p564_Bruttomesso_oai |
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I28-R145-paper_14203049_v5_n3_p564_Bruttomesso_oai2020-10-19 Bruttomesso, A.C. Gros, E.G. 2000 Diosgeninlactone (1), a natural product from Solanum vespertilio, was stereo-selectively synthesized in high yield from 3β-hydroxy-5-androstene. Fil:Bruttomesso, A.C. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. application/pdf http://hdl.handle.net/20.500.12110/paper_14203049_v5_n3_p564_Bruttomesso info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar Molecules 2000;5(3):564-565 (20) 3beta,16beta dihydroxy 5 pregnen 20,16 carbolactone 3beta hydroxy 5 androsterone alkaloid derivative androsterone diosgenin hydroxyl group lactone sapogenin steroid unclassified drug catabolism cis isomer conference paper correlation analysis extraction fruit molecular dynamics molecular interaction molecular mechanics plant plant yield probability protein degradation protein isolation solanum vespertilio stereochemistry synthesis technique tomato vegetable First synthesis of (20S) 3β,16β-dihydroxy-5-pregnen-20,16- carbolactone (diosgeninlactone) info:eu-repo/semantics/article info:ar-repo/semantics/artículo info:eu-repo/semantics/publishedVersion http://repositoriouba.sisbi.uba.ar/gsdl/cgi-bin/library.cgi?a=d&c=artiaex&d=paper_14203049_v5_n3_p564_Bruttomesso_oai |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-145 |
| collection |
Repositorio Digital de la Universidad de Buenos Aires (UBA) |
| topic |
(20) 3beta,16beta dihydroxy 5 pregnen 20,16 carbolactone 3beta hydroxy 5 androsterone alkaloid derivative androsterone diosgenin hydroxyl group lactone sapogenin steroid unclassified drug catabolism cis isomer conference paper correlation analysis extraction fruit molecular dynamics molecular interaction molecular mechanics plant plant yield probability protein degradation protein isolation solanum vespertilio stereochemistry synthesis technique tomato vegetable |
| spellingShingle |
(20) 3beta,16beta dihydroxy 5 pregnen 20,16 carbolactone 3beta hydroxy 5 androsterone alkaloid derivative androsterone diosgenin hydroxyl group lactone sapogenin steroid unclassified drug catabolism cis isomer conference paper correlation analysis extraction fruit molecular dynamics molecular interaction molecular mechanics plant plant yield probability protein degradation protein isolation solanum vespertilio stereochemistry synthesis technique tomato vegetable Bruttomesso, A.C. Gros, E.G. First synthesis of (20S) 3β,16β-dihydroxy-5-pregnen-20,16- carbolactone (diosgeninlactone) |
| topic_facet |
(20) 3beta,16beta dihydroxy 5 pregnen 20,16 carbolactone 3beta hydroxy 5 androsterone alkaloid derivative androsterone diosgenin hydroxyl group lactone sapogenin steroid unclassified drug catabolism cis isomer conference paper correlation analysis extraction fruit molecular dynamics molecular interaction molecular mechanics plant plant yield probability protein degradation protein isolation solanum vespertilio stereochemistry synthesis technique tomato vegetable |
| description |
Diosgeninlactone (1), a natural product from Solanum vespertilio, was stereo-selectively synthesized in high yield from 3β-hydroxy-5-androstene. |
| format |
Artículo Artículo publishedVersion |
| author |
Bruttomesso, A.C. Gros, E.G. |
| author_facet |
Bruttomesso, A.C. Gros, E.G. |
| author_sort |
Bruttomesso, A.C. |
| title |
First synthesis of (20S) 3β,16β-dihydroxy-5-pregnen-20,16- carbolactone (diosgeninlactone) |
| title_short |
First synthesis of (20S) 3β,16β-dihydroxy-5-pregnen-20,16- carbolactone (diosgeninlactone) |
| title_full |
First synthesis of (20S) 3β,16β-dihydroxy-5-pregnen-20,16- carbolactone (diosgeninlactone) |
| title_fullStr |
First synthesis of (20S) 3β,16β-dihydroxy-5-pregnen-20,16- carbolactone (diosgeninlactone) |
| title_full_unstemmed |
First synthesis of (20S) 3β,16β-dihydroxy-5-pregnen-20,16- carbolactone (diosgeninlactone) |
| title_sort |
first synthesis of (20s) 3β,16β-dihydroxy-5-pregnen-20,16- carbolactone (diosgeninlactone) |
| publishDate |
2000 |
| url |
http://hdl.handle.net/20.500.12110/paper_14203049_v5_n3_p564_Bruttomesso http://repositoriouba.sisbi.uba.ar/gsdl/cgi-bin/library.cgi?a=d&c=artiaex&d=paper_14203049_v5_n3_p564_Bruttomesso_oai |
| work_keys_str_mv |
AT bruttomessoac firstsynthesisof20s3b16bdihydroxy5pregnen2016carbolactonediosgeninlactone AT groseg firstsynthesisof20s3b16bdihydroxy5pregnen2016carbolactonediosgeninlactone |
| _version_ |
1766026766333247488 |