N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
The title compound, C 9H 14N +· CHB 11Cl 11 -, was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkyl-pyridinium and dialkyl-imidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinate...
Guardado en:
Autores principales: | , , , , |
---|---|
Formato: | Artículo publishedVersion |
Publicado: |
2011
|
Materias: | |
Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_01082701_v67_n10_po417_Suarez http://repositoriouba.sisbi.uba.ar/gsdl/cgi-bin/library.cgi?a=d&c=artiaex&d=paper_01082701_v67_n10_po417_Suarez_oai |
Aporte de: |
id |
I28-R145-paper_01082701_v67_n10_po417_Suarez_oai |
---|---|
record_format |
dspace |
spelling |
I28-R145-paper_01082701_v67_n10_po417_Suarez_oai2020-10-19 Suarez, S.A. Foi, A. Eady, S. Larsen, A. Doctorovich, F. 2011 The title compound, C 9H 14N +· CHB 11Cl 11 -, was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkyl-pyridinium and dialkyl-imidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinated carborane anion. The structure consists of one N-butyl-pyridinium cation counterbalanced by one perchlorinated carborane cage anion per asymmetric unit. By changing the counter-ion, different packings are observed, and to try to understand this the new structure is compared with five similar compounds. © 2011 International Union of Crystallography. Fil:Suarez, S.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. application/pdf http://hdl.handle.net/20.500.12110/paper_01082701_v67_n10_po417_Suarez info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar Acta Crystallogr Sect C Cryst Struct Commun 2011;67(10):o417-o420 Asymmetric unit Carborane anions Carborane cages Counterions Pyridinium salts Title compounds Positive ions Negative ions N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds info:eu-repo/semantics/article info:ar-repo/semantics/artículo info:eu-repo/semantics/publishedVersion http://repositoriouba.sisbi.uba.ar/gsdl/cgi-bin/library.cgi?a=d&c=artiaex&d=paper_01082701_v67_n10_po417_Suarez_oai |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-145 |
collection |
Repositorio Digital de la Universidad de Buenos Aires (UBA) |
topic |
Asymmetric unit Carborane anions Carborane cages Counterions Pyridinium salts Title compounds Positive ions Negative ions |
spellingShingle |
Asymmetric unit Carborane anions Carborane cages Counterions Pyridinium salts Title compounds Positive ions Negative ions Suarez, S.A. Foi, A. Eady, S. Larsen, A. Doctorovich, F. N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds |
topic_facet |
Asymmetric unit Carborane anions Carborane cages Counterions Pyridinium salts Title compounds Positive ions Negative ions |
description |
The title compound, C 9H 14N +· CHB 11Cl 11 -, was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkyl-pyridinium and dialkyl-imidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinated carborane anion. The structure consists of one N-butyl-pyridinium cation counterbalanced by one perchlorinated carborane cage anion per asymmetric unit. By changing the counter-ion, different packings are observed, and to try to understand this the new structure is compared with five similar compounds. © 2011 International Union of Crystallography. |
format |
Artículo Artículo publishedVersion |
author |
Suarez, S.A. Foi, A. Eady, S. Larsen, A. Doctorovich, F. |
author_facet |
Suarez, S.A. Foi, A. Eady, S. Larsen, A. Doctorovich, F. |
author_sort |
Suarez, S.A. |
title |
N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds |
title_short |
N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds |
title_full |
N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds |
title_fullStr |
N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds |
title_full_unstemmed |
N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds |
title_sort |
n-butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds |
publishDate |
2011 |
url |
http://hdl.handle.net/20.500.12110/paper_01082701_v67_n10_po417_Suarez http://repositoriouba.sisbi.uba.ar/gsdl/cgi-bin/library.cgi?a=d&c=artiaex&d=paper_01082701_v67_n10_po417_Suarez_oai |
work_keys_str_mv |
AT suarezsa nbutylpyridiniumundecachlorocarbadodecaborateandcomparisonwithsimilarcompounds AT foia nbutylpyridiniumundecachlorocarbadodecaborateandcomparisonwithsimilarcompounds AT eadys nbutylpyridiniumundecachlorocarbadodecaborateandcomparisonwithsimilarcompounds AT larsena nbutylpyridiniumundecachlorocarbadodecaborateandcomparisonwithsimilarcompounds AT doctorovichf nbutylpyridiniumundecachlorocarbadodecaborateandcomparisonwithsimilarcompounds |
_version_ |
1766026662933168128 |