A kinetic study of the aqueous phase oxidation of di-μ-oxo-bis(L-cysteine)-oxomolybdenum(V) by molecular oxygen
The molecular oxygen-mediated decomposition of the binuclear complex, prepared from oxomolybdate(V) and L-(+)-cysteine, was studied spectrophotometrically at pH 3.5–5.6. The formation of MoVI was detected. The effects of pH and [O2] on the decomposition kinetics are given by the equation: [fórmula]...
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| Autores principales: | , , , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
1998
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| Materias: | |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/145879 |
| Aporte de: |
| Sumario: | The molecular oxygen-mediated decomposition of the binuclear complex, prepared from oxomolybdate(V) and L-(+)-cysteine, was studied spectrophotometrically at pH 3.5–5.6. The formation of MoVI was detected. The effects of pH and [O2] on the decomposition kinetics are given by the equation: [fórmula] with the apparent first order rate constant, kobs, expressed in s−1 and the concentrations in molar units. |
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