Crystal structure and EPR spectrum of dimeric di-μ-azide-bis[cyanide(N,N-diethylethylenediamine)]-copper(II), [Cu(N₃)(NCO)(diEten)]₂

The title compound, [Cu(N₃)(NCO)(C₆H₁₆N₂)]₂, crystallizes in the space groupP2₁/n, witha=8.336(1),b=17.405(3),c=8.376(1) Å, β=109.73(2)o andZ=4. The molecules are arranged as centrosymmetric dimers in which two azide ligands bridge neighboring copper ions in an asymmetric head-on fashion. The Cu(II)...

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Autores principales: Piro, Oscar Enrique, Castellano, Eduardo Ernesto, Zukerman Schpector, Julio, De Simone, C. A., Martino, D. M., Steren, C. A.
Formato: Articulo
Lenguaje:Inglés
Publicado: 1997
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Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/139042
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