Kinetics and mechanism of the hydrogen-evolution reaction on mercury in HCl-dimethylsulphoxide solutions
Rapid galvanostatic and potentiostatic stationary E/I curves, E/time characteristics at current interruption and electrode capacitance measurements were made to investigate hydrogen-ion discharge on mercury in HCl-DMSO solutions, with and without the addition of LiCl as supporting electrolyte. Kinet...
Guardado en:
| Autores principales: | , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
1973
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| Materias: | |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/121727 |
| Aporte de: |
| Sumario: | Rapid galvanostatic and potentiostatic stationary E/I curves, E/time characteristics at current interruption and electrode capacitance measurements were made to investigate hydrogen-ion discharge on mercury in HCl-DMSO solutions, with and without the addition of LiCl as supporting electrolyte. Kinetic parameters and their temperature and concentration dependences are discussed in terms of the initial electron-trnsfer reaction as rate-determining. |
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