Upgrading of Tall Fescue Grass Pyrolytic Bioliquid and Catalytic Valorization of The Biofurfural Obtained

The production of added value products following catalytic hydrogenation reactions of bioliquids was studied. These bioliquids were obtained from the pyrolysis of raw and acid-treated (H3PO4) Tall Fescue (Fescue arundinacea) waste. Before the pyrolytic test, the biomass samples were analyzed by a mi...

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Autores principales: Musci, Juan J., Casoni, Andrés I., Gutiérrez, Victoria S., Ocsachoque, Marco A., Merlo, Andrea B., Volpe, María A., Lick, Ileana D., Casella, Mónica L.
Formato: Artículo publishedVersion
Lenguaje:Inglés
Publicado: 2024
Materias:
Biomass
Furfural
Heterogeneous Catalysis Hydrogenation
Pyrolysis
Acceso en línea:http://repositorio.unnoba.edu.ar/xmlui/handle/23601/839
Aporte de:
Re DI Repositorio Digital UNNOBA de Universidad Nacional del Noroeste de la Provincia de Buenos Aires
id I103-R405-23601-839
record_format dspace
institution Universidad Nacional del Noroeste de la Provincia de Buenos Aires
institution_str I-103
repository_str R-405
collection Re DI Repositorio Digital UNNOBA
language Inglés
topic Biomass
Furfural
Heterogeneous Catalysis Hydrogenation
Pyrolysis
spellingShingle Biomass
Furfural
Heterogeneous Catalysis Hydrogenation
Pyrolysis
Musci, Juan J.
Casoni, Andrés I.
Gutiérrez, Victoria S.
Ocsachoque, Marco A.
Merlo, Andrea B.
Volpe, María A.
Lick, Ileana D.
Casella, Mónica L.
Upgrading of Tall Fescue Grass Pyrolytic Bioliquid and Catalytic Valorization of The Biofurfural Obtained
topic_facet Biomass
Furfural
Heterogeneous Catalysis Hydrogenation
Pyrolysis
description The production of added value products following catalytic hydrogenation reactions of bioliquids was studied. These bioliquids were obtained from the pyrolysis of raw and acid-treated (H3PO4) Tall Fescue (Fescue arundinacea) waste. Before the pyrolytic test, the biomass samples were analyzed by a micro thermogravimetric analysis coupled with FTIR spectroscopy (TGA-IR), which enables the chemical identification of functional groups of gaseous molecules originated by solid/gas transformations. From these results, the pyrolysis temperature was selected, and bench scale pyrolysis reactions were carried out. The pyrolysis bioliquids showed high furfural concentration, 46 and 70% for fescue and acid washed fescue, respectively. The bioliquid with the highest furfural concentration was catalytically hydrogenated in aqueous phase. A batch reactor was employed, with Ru/C and Ru-Sn/C catalysts to produce high added value alcohols.
format Artículo
Artículo
publishedVersion
Artículo
Artículo
publishedVersion
Artículo
Artículo
publishedVersion
author Musci, Juan J.
Casoni, Andrés I.
Gutiérrez, Victoria S.
Ocsachoque, Marco A.
Merlo, Andrea B.
Volpe, María A.
Lick, Ileana D.
Casella, Mónica L.
author_facet Musci, Juan J.
Casoni, Andrés I.
Gutiérrez, Victoria S.
Ocsachoque, Marco A.
Merlo, Andrea B.
Volpe, María A.
Lick, Ileana D.
Casella, Mónica L.
author_sort Musci, Juan J.
title Upgrading of Tall Fescue Grass Pyrolytic Bioliquid and Catalytic Valorization of The Biofurfural Obtained
title_short Upgrading of Tall Fescue Grass Pyrolytic Bioliquid and Catalytic Valorization of The Biofurfural Obtained
title_full Upgrading of Tall Fescue Grass Pyrolytic Bioliquid and Catalytic Valorization of The Biofurfural Obtained
title_fullStr Upgrading of Tall Fescue Grass Pyrolytic Bioliquid and Catalytic Valorization of The Biofurfural Obtained
title_full_unstemmed Upgrading of Tall Fescue Grass Pyrolytic Bioliquid and Catalytic Valorization of The Biofurfural Obtained
title_sort upgrading of tall fescue grass pyrolytic bioliquid and catalytic valorization of the biofurfural obtained
publishDate 2024
url http://repositorio.unnoba.edu.ar/xmlui/handle/23601/839
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spelling I103-R405-23601-8392024-08-15T19:02:14Z Upgrading of Tall Fescue Grass Pyrolytic Bioliquid and Catalytic Valorization of The Biofurfural Obtained Musci, Juan J. Casoni, Andrés I. Gutiérrez, Victoria S. Ocsachoque, Marco A. Merlo, Andrea B. Volpe, María A. Lick, Ileana D. Casella, Mónica L. Biomass Furfural Heterogeneous Catalysis Hydrogenation Pyrolysis The production of added value products following catalytic hydrogenation reactions of bioliquids was studied. These bioliquids were obtained from the pyrolysis of raw and acid-treated (H3PO4) Tall Fescue (Fescue arundinacea) waste. Before the pyrolytic test, the biomass samples were analyzed by a micro thermogravimetric analysis coupled with FTIR spectroscopy (TGA-IR), which enables the chemical identification of functional groups of gaseous molecules originated by solid/gas transformations. From these results, the pyrolysis temperature was selected, and bench scale pyrolysis reactions were carried out. The pyrolysis bioliquids showed high furfural concentration, 46 and 70% for fescue and acid washed fescue, respectively. The bioliquid with the highest furfural concentration was catalytically hydrogenated in aqueous phase. A batch reactor was employed, with Ru/C and Ru-Sn/C catalysts to produce high added value alcohols. Fil: Musci, Juan J. Universidad Nacional del Noroeste de la Provincia de Buenos Aires. Departamento de Ciencias Básicas y Experimentales; Argentina. Fil: Musci, Juan J. Centro de Investigaciones y Transferencia del Noroeste de la Provincia de Buenos Aires; Argentina. Fil: Casoni, Andrés I. Centro Científico Tecnológico de Consejo Nacional de Investigaciones Científicas y Técnicas -Bahía Blanca. Planta Piloto de Ingeniería Química; Argentina. Fil: Gutiérrez, Victoria S. Centro Científico Tecnológico de Consejo Nacional de Investigaciones Científicas y Técnicas -Bahía Blanca. Planta Piloto de Ingeniería Química; Argentina. Fil: Ocsachoque, Marco A. Centro Científico Tecnológico de Consejo Nacional de Investigaciones Científicas y Técnicas -La Plata. Universidad Nacional de La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas “Dr. Jorge J.Ronco”; Argentina. Fil: Merlo, Andrea B. Centro Científico Tecnológico de Consejo Nacional de Investigaciones Científicas y Técnicas -La Plata. Universidad Nacional de La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas “Dr. Jorge J.Ronco”; Argentina. Fil: Volpe, María A. Centro Científico Tecnológico de Consejo Nacional de Investigaciones Científicas y Técnicas -Bahía Blanca. Planta Piloto de Ingeniería Química; Argentina. Fil: Lick, leana D. Centro Científico Tecnológico de Consejo Nacional de Investigaciones Científicas y Técnicas -La Plata. Universidad Nacional de La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas “Dr. Jorge J.Ronco”; Argentina. Fil: Casella, Mónica L. Universidad Nacional del Noroeste de la Provincia de Buenos Aires. Departamento de Ciencias Básicas y Experimentales; Argentina. Fil: Casella, Mónica L. Centro Científico Tecnológico de Consejo Nacional de Investigaciones Científicas y Técnicas -La Plata. Universidad Nacional de La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas “Dr. Jorge J.Ronco”; Argentina. Con referato 2024-08-15T19:01:14Z 2024-08-15T19:01:14Z 2022 info:eu-repo/semantics/article info:ar-repo/semantics/artículo info:eu-repo/semantics/publishedVersion info:eu-repo/semantics/article info:ar-repo/semantics/artículo info:eu-repo/semantics/publishedVersion info:eu-repo/semantics/article info:ar-repo/semantics/artículo info:eu-repo/semantics/publishedVersion Musci, J. J., Casoni, A. I., Gutiérrez, V. S., Ocsachoque, M. A., Merlo, A. B., Volpe, M. A., Lick, I. y Casella, M. L. (2022). Upgrading of Tall Fescue Grass Pyrolytic Bioliquid and Catalytic Valorization of The Biofurfural Obtained. ChemistrySelect, 7(41), e202202233. 2365-6549 http://repositorio.unnoba.edu.ar/xmlui/handle/23601/839 eng info:eu-repo/grantAgreement/UNNOBA/SIB/2022. info:eu-repo/grantAgreement/UNLP/X903/Expte 100–1282 19 info:eu-repo/grantAgreement/CONICET/PUE 2018/8085-17 info:eu-repo/grantAgreement/ANPCyT FONCyT/PICT 2019-1962 doi.org/10.1002/slct.202202233 info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ application/pdf application/pdf Chemistry Select

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