Effectiveness of Cupressus sempervirens cones as biosorbent for the removal of basic dyes from aqueous solutions in batch and dynamic modes

The feasibility of using cypress cone chips from Cupressus sempervirens as a low-cost biosorbent for the removal of two representative basic dyes, methylene blue (MB) and rhodamine B (RhB), from aqueous solutions was investigated in batch and continuous modes. Dyes biosorption was strongly dependent...

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Autor principal: Fernandez, M.E
Otros Autores: Nunell, G.V, Bonelli, P.R, Cukierman, A.L
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2010
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024 7 |2 scopus  |a 2-s2.0-77956154288 
024 7 |2 cas  |a methylene blue, 61-73-4; rhodamine B, 81-88-9; Coloring Agents; Methylene Blue, 61-73-4; Rhodamines; Solutions; rhodamine B, 14899-08-2 
040 |a Scopus  |b spa  |c AR-BaUEN  |d AR-BaUEN 
030 |a BIRTE 
100 1 |a Fernandez, M.E. 
245 1 0 |a Effectiveness of Cupressus sempervirens cones as biosorbent for the removal of basic dyes from aqueous solutions in batch and dynamic modes 
260 |c 2010 
270 1 0 |m Cukierman, A.L.; Departamento de Tecnología Farmacéutica, Facultad de Farmacia y Bioquímica, Universidad de Buenos Aires, Junín 956, (C113AAD) Buenos Aires, Argentina; email: analea@di.fcen.uba.ar 
506 |2 openaire  |e Política editorial 
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520 3 |a The feasibility of using cypress cone chips from Cupressus sempervirens as a low-cost biosorbent for the removal of two representative basic dyes, methylene blue (MB) and rhodamine B (RhB), from aqueous solutions was investigated in batch and continuous modes. Dyes biosorption was strongly dependent on the solution's pH. Sorption kinetics was determined and properly described by the pseudo-second-order rate model. Experimental equilibrium isotherms fitted the Langmuir model, showing maximum biosorption capacities of 0.62. mmol/g for MB and 0.24. mmol/g for RhB. Competitive experiments from a binary solution of the dyes demonstrated the preference of the cone chips for biosorbing MB. Very low desorption efficiencies were obtained for both dyes. Dynamic experiments showed that the breakthrough time was three times higher for MB biosorption than for RhB for the same conditions. Breakthrough curves were properly represented by a mathematical model. © 2010 Elsevier Ltd.  |l eng 
536 |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica 
536 |a Detalles de la financiación: Universidad de Buenos Aires 
536 |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas 
536 |a Detalles de la financiación: The authors gratefully acknowledge Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET) , Universidad de Buenos Aires (UBA) , and Agencia Nacional de Promoción Científica y Tecnológica (ANPCyT-FONCyT) from Argentina, for financial support. 
593 |a Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energia, PINMATE, Departamento de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Intendente Güiraldes 2620, Ciudad Universitaria, C1428BGA Buenos Aires, Argentina 
593 |a Cátedra de Farmacotecnia II, Departamento de Tecnología Farmacéutica, Facultad de Farmacia y Bioquímica, Universidad de Buenos Aires, Junín 956, C113AAD Buenos Aires, Argentina 
690 1 0 |a BASIC DYES 
690 1 0 |a BIOSORPTION 
690 1 0 |a CYPRESS CONE CHIPS 
690 1 0 |a TEXTILE WASTEWATER TREATMENT 
690 1 0 |a UP-FLOW COLUMN 
690 1 0 |a AQUEOUS SOLUTIONS 
690 1 0 |a BASIC DYES 
690 1 0 |a BINARY SOLUTIONS 
690 1 0 |a BIOSORBENTS 
690 1 0 |a BIOSORPTION CAPACITY 
690 1 0 |a BREAK THROUGH CURVE 
690 1 0 |a BREAKTHROUGH TIME 
690 1 0 |a COMPETITIVE EXPERIMENTS 
690 1 0 |a CONTINUOUS MODE 
690 1 0 |a CYPRESS CONE CHIPS 
690 1 0 |a DESORPTION EFFICIENCY 
690 1 0 |a DYNAMIC EXPERIMENT 
690 1 0 |a DYNAMIC MODES 
690 1 0 |a EQUILIBRIUM ISOTHERMS 
690 1 0 |a LANGMUIR MODELS 
690 1 0 |a METHYLENE BLUE 
690 1 0 |a PSEUDO SECOND ORDER RATE MODEL 
690 1 0 |a RHODAMINE B 
690 1 0 |a SORPTION KINETICS 
690 1 0 |a TEXTILE WASTEWATER TREATMENT 
690 1 0 |a UP-FLOW COLUMN 
690 1 0 |a ADSORPTION 
690 1 0 |a BIOSORPTION 
690 1 0 |a DESORPTION 
690 1 0 |a DYES 
690 1 0 |a MATHEMATICAL MODELS 
690 1 0 |a SOLUTIONS 
690 1 0 |a TEXTILES 
690 1 0 |a WASTEWATER 
690 1 0 |a WASTEWATER TREATMENT 
690 1 0 |a WATER TREATMENT PLANTS 
690 1 0 |a STRIPPING (DYES) 
690 1 0 |a ABSORBENT 
690 1 0 |a CYPRESS CONE CHIP 
690 1 0 |a METHYLENE BLUE 
690 1 0 |a RHODAMINE B 
690 1 0 |a UNCLASSIFIED DRUG 
690 1 0 |a ADSORPTION 
690 1 0 |a AQUEOUS SOLUTION 
690 1 0 |a BREAKTHROUGH CURVE 
690 1 0 |a CONIFEROUS TREE 
690 1 0 |a DESORPTION 
690 1 0 |a DYE 
690 1 0 |a EXPERIMENTAL STUDY 
690 1 0 |a FEASIBILITY STUDY 
690 1 0 |a ISOTHERM 
690 1 0 |a NUMERICAL MODEL 
690 1 0 |a POLLUTANT REMOVAL 
690 1 0 |a REACTION KINETICS 
690 1 0 |a TEXTILE INDUSTRY 
690 1 0 |a WASTEWATER 
690 1 0 |a AQUEOUS SOLUTION 
690 1 0 |a ARTICLE 
690 1 0 |a BIOSORPTION 
690 1 0 |a CUPRESSUS 
690 1 0 |a CUPRESSUS SEMPERVIREN 
690 1 0 |a DESORPTION 
690 1 0 |a ISOTHERM 
690 1 0 |a MATHEMATICAL MODEL 
690 1 0 |a PRIORITY JOURNAL 
690 1 0 |a UPFLOW REACTOR 
690 1 0 |a ADSORPTION 
690 1 0 |a BIODEGRADATION, ENVIRONMENTAL 
690 1 0 |a COLORING AGENTS 
690 1 0 |a CUPRESSUS 
690 1 0 |a HYDROGEN-ION CONCENTRATION 
690 1 0 |a KINETICS 
690 1 0 |a METHYLENE BLUE 
690 1 0 |a MODELS, CHEMICAL 
690 1 0 |a RHODAMINES 
690 1 0 |a SOLUTIONS 
690 1 0 |a TEMPERATURE 
690 1 0 |a WATER PURIFICATION 
690 1 0 |a CUPRESSUS 
690 1 0 |a CUPRESSUS SEMPERVIRENS 
650 1 7 |2 spines  |a PH 
650 1 7 |2 spines  |a PH 
700 1 |a Nunell, G.V. 
700 1 |a Bonelli, P.R. 
700 1 |a Cukierman, A.L. 
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