Combination strategy using pure enzymes and whole cells as biocatalysts for the preparation of 2-hydroxyesters and lactones from 2-oxoglutaric acid
An innovative combination strategy that uses pure enzymes and whole microbial cells in the same process was used to prepare enantiomerically pure 3-carboxyalkyl-γ-butyrolactones and several alkyl esters of 2-hydroxyglutarate from 2-oxoglutaric acid. An innovative combination strategy that uses pure...
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| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
2004
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
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| LEADER | 06786caa a22009137a 4500 | ||
|---|---|---|---|
| 001 | PAPER-4358 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518203354.0 | ||
| 008 | 190411s2004 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-9644295716 | |
| 024 | 7 | |2 cas |a 2 oxoglutaric acid, 328-50-7; triacylglycerol lipase, 9001-62-1 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a TASYE | ||
| 100 | 1 | |a Rustoy, E.M. | |
| 245 | 1 | 0 | |a Combination strategy using pure enzymes and whole cells as biocatalysts for the preparation of 2-hydroxyesters and lactones from 2-oxoglutaric acid |
| 260 | |c 2004 | ||
| 270 | 1 | 0 | |m Depto. de Quim. Organ. Y UMYMFOR, Fac. de Ciencias Exactas Y Naturales, Univ. Buenos Aires, Pabellon 2, P.Argentina; email: alib@qo.fcen.uba.ar |
| 506 | |2 openaire |e Política editorial | ||
| 504 | |a Garciía, C., Martin, T., Martin, V.S., (2001) J. Org. Chem., 66, pp. 1420-1428 | ||
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| 504 | |a Mangone, C.P., Pereyra, E.N., Argimon, S., Moreno, S., Baldessari, A., (2002) Enzyme Microb. Technol., 30, pp. 596-601 | ||
| 504 | |a Baldessari, A., Gros, E.G., Argentine Patent AR 002219B1; Bruttomesso, A.C., Tiscornia, A., Baldessari, A., (2004) Biocatal. Biotransform., 22, pp. 215-220 | ||
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| 520 | 3 | |a An innovative combination strategy that uses pure enzymes and whole microbial cells in the same process was used to prepare enantiomerically pure 3-carboxyalkyl-γ-butyrolactones and several alkyl esters of 2-hydroxyglutarate from 2-oxoglutaric acid. An innovative combination strategy that uses pure enzymes and whole microbial cells in the same process was used to prepare enantiomerically pure 3-carboxyalkyl-γ-butyrolactones and several alkyl esters of 2-hydroxyglutarates from 2-oxoglutaric acid. The method involves two consecutive biocatalytic steps. The first step, which converts the 2-oxoglutaric acid into the corresponding dialkyl esters, was catalyzed by a lipase. Then in the second step, by microbial reduction of the dialkyl-2-oxoglutarates, it is possible to obtain 3-carboxyalkyl-γ- butyrolactones or 2-hydroxyesters depending on the length of the chain in the alkyl moiety of the esters and on the fresh or lyophilized status of the cells. © 2004 Elsevier Ltd. All rights reserved. |l eng | |
| 536 | |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica | ||
| 536 | |a Detalles de la financiación: We thank UBA and ANPCyT for partial financial support. The authors gratefully acknowledge M. M. Rivero for his assistance in GC analysis. | ||
| 593 | |a Depto. de Quim. Organ. Y UMYMFOR, Fac. de Ciencias Exactas Y Naturales, Univ. Buenos Aires, Pabellon 2, P., Argentina | ||
| 593 | |a Depto. de Quím. Biol., Fac. de Ciencias Exactas Y Naturales, Univ. Buenos Aires, Pabellon 2, P., Argentina | ||
| 690 | 1 | 0 | |a 2 OXOGLUTARIC ACID |
| 690 | 1 | 0 | |a ESTER DERIVATIVE |
| 690 | 1 | 0 | |a FUNGAL ENZYME |
| 690 | 1 | 0 | |a LACTONE DERIVATIVE |
| 690 | 1 | 0 | |a TRIACYLGLYCEROL LIPASE |
| 690 | 1 | 0 | |a ACIDIFICATION |
| 690 | 1 | 0 | |a ALKYLATION |
| 690 | 1 | 0 | |a ARTICLE |
| 690 | 1 | 0 | |a BIOCATALYST |
| 690 | 1 | 0 | |a CATALYSIS |
| 690 | 1 | 0 | |a DERIVATIZATION |
| 690 | 1 | 0 | |a DRUG SYNTHESIS |
| 690 | 1 | 0 | |a ENANTIOMER |
| 690 | 1 | 0 | |a ENZYME MECHANISM |
| 690 | 1 | 0 | |a ESTERIFICATION |
| 690 | 1 | 0 | |a LACTONIZATION |
| 690 | 1 | 0 | |a PRIORITY JOURNAL |
| 700 | 1 | |a Pereyra, E.N. | |
| 700 | 1 | |a Moreno, S. | |
| 700 | 1 | |a Baldessari, A. | |
| 773 | 0 | |d 2004 |g v. 15 |h pp. 3763-3768 |k n. 23 |p Tetrahedron Asymmetry |x 09574166 |w (AR-BaUEN)CENRE-562 |t Tetrahedron Asymmetry | |
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| 856 | 4 | 0 | |u https://doi.org/10.1016/j.tetasy.2004.10.013 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_09574166_v15_n23_p3763_Rustoy |y Handle |
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