Dielectric properties of binary systems 10. Ideal dielectric behavior and excess dielectric properties.

A simple model is proposed to describe excess dielectric properties that is based on the additivity of electrical susceptibilities of species in a mixture. Since this requires a definition for the ideal dielectric behavior of a liquid mixture, a thermodynamicaly ideal mixture was considered to be un...

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Autor principal: Buep, Adrián Hugo
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1992
Acceso en línea:Registro en Scopus
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245 1 0 |a Dielectric properties of binary systems 10. Ideal dielectric behavior and excess dielectric properties. 
260 |c 1992 
270 1 0 |m Buep, A.H.; Departamento de Fisica. Facultad de Ciencias Exactas, Naturales. Universidad de Buenos Aires. Pabellón I. Ciudad Universitaria., 1428 Buenos Aires, Argentina 
504 |a Prigogine, Defay, (1973) Chemical Thermodynamics, , Longman, London 
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504 |a McGlashan, Stubley, Watts, Enthalpies of mixing and complex formation of carbon tetrachloride with benzene, toluene, p-xylene, and mesitylene (1969) Journal of the Chemical Society A: Inorganic, Physical, Theoretical, p. 673 
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504 |a Stokes, (1977) J. Chem. Soc. Faraday I, 73, p. 1140 
504 |a Stokes, French, (1980) J. Chem. Soc. Faraday I, 76, p. 537 
504 |a Thiebaut, Rivail, Barriol, (1972) J. Chem. Soc. Faraday Trans. 2, 68, p. 1253 
504 |a Rivail, Thiebaut, Dielectric studies of non-electrolyte solutions. Part 2.?Non-linear behaviour of associated liquids. Application to the study of pyridine?chloroform interactions (1973) Journal of the Chemical Society, Faraday Transactions 2, 70, p. 430 
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506 |2 openaire  |e Política editorial 
520 3 |a A simple model is proposed to describe excess dielectric properties that is based on the additivity of electrical susceptibilities of species in a mixture. Since this requires a definition for the ideal dielectric behavior of a liquid mixture, a thermodynamicaly ideal mixture was considered to be under the effect of an applied electrical field. The resulting formalism being then independent of any particular dielectric model, as well as of the polarity of the components. The developed treatment has a general nature, is applicable to homogeneous isotropic liquid mixtures and allows to describe dielectric excesses as the sum of several contributions. Its usefulness is verified in the CCl4 + cyclohexane, CCl4 + benzene, CCl4 + p-xylene and CCl4 + toluene mixtures at 303.15 K. © 1992.  |l eng 
593 |a Departamento de Fisica. Facultad de Ciencias Exactas, Naturales. Universidad de Buenos Aires. Pabellón I. Ciudad Universitaria., 1428 Buenos Aires, Argentina 
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