Constituents of the essential oil of lippia integrifolia (Griseb.) Hieron. (Verbenaceae)

The essential oil of Lippia integrifolia was analysed by capillary GC interfaced with MS. The main constituents were isolated by using column chromatography and reversed-phase liquid chromatography and their structures established by spectroscopic methods. The major constituent of the oil is lippifo...

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Autor principal: De Lampasona, M.E.P
Otros Autores: De Fenik, I.S, Catalán, C.A.N, Dartayet, G.H, Gros, E.G, Cerda-García-Rojas, C.M, Mora-Pérez, Y., Joseph-Nathan, P.
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: International Society for Horticultural Science 1999
Acceso en línea:Registro en Scopus
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100 1 |a De Lampasona, M.E.P. 
245 1 0 |a Constituents of the essential oil of lippia integrifolia (Griseb.) Hieron. (Verbenaceae) 
260 |b International Society for Horticultural Science  |c 1999 
506 |2 openaire  |e Política editorial 
504 |a Catalan, C.A., Iglesias, D.A., Retamar, J., Iturraspe, J., Dartayet, G.H., Gros, E., A sesquiterpene diketone from Lippia integrifolia (1983) Phytochemistry, 22, pp. 1507-1508 
504 |a Catalan, C.A., De Fenik, J.S., Dartayet, G.H., Gros, E., Integrifolian-l,5-dione and a revised structure for " africanone", biogenetically related sesquiterpene from Lippia integrifolia (1991) Phytochemistry, 30, pp. 1323-1326 
504 |a Catalan, C.A.N., De Fenik, J.S., De Arriazu, P.J., Kokke, W.C.M.C., 4,5-seco-african-4,5-dione from Lippia integrifolia (1992) Phytochemistry, 31, pp. 4025-4026 
504 |a Catalan, C.A., De Fenik, J.S., Cerda-García-Rojas, C.M., Mora-Pérez, Y., Joseph-Nathan, P., Total assignment of the 13C NMR spectra of integrifolian-l,5-dione and derivatives by 2D spectroscopy (1993) Spectroscopy, 11, pp. 1-8 
504 |a Catalan, C.A.N., De Lampasona, M.P., De Fenik, J.S., Cerda-García-Rojas, C.M., Joseph-Nathan, P., Structure and Conformation of a Humulendione from Lippia integrifolia (1993) Journal of Natural Products, 56, pp. 381-385 
504 |a Catalan, C.A.N., De Lampasona, M.P., De Fenik, J.S., Cerda-García-Rojas, C.M., Mora-Pérez, Y., Joseph-Nathan, P., Minor Constituents of Lippia integrifolia (1994) Journal of Natural Products, 57, pp. 206-210 
504 |a Catalan, C.A.N., De Lampasona, M.P., Cerda-García-Rojas, C.M., Joseph-Nathan, P., Trace Constituents of Lippia integrifolia (1995) Journal of Natural Products, 58, pp. 1713-1717 
504 |a Dartayet, G., Catalan, C.A., Rater, J.A., Gros, E.G., Sesquiterpenoids from Lippia integrifolia -africanone-, a tricyclic sesquiterpene ketone (1984) Phytochemistry, 23, pp. 688-689 
504 |a Toursarkissian, M., (1980) Plantas Medicinales de la Argentina. Sus Nombres Botánicos, Vulgares, Usos y Distribución Geográfica, p. 135. , Editorial Hemisferio Sur, Buenos Aires 
520 3 |a The essential oil of Lippia integrifolia was analysed by capillary GC interfaced with MS. The main constituents were isolated by using column chromatography and reversed-phase liquid chromatography and their structures established by spectroscopic methods. The major constituent of the oil is lippifoli-l(6)-en-5-one (4), a ketone based on a new sesquiterpene skeleton named lippifoliane. Ketone 4 biogenetically derives from integrifolian-1,5-dione (2), which is also a constituent of the oil. In addition to several known mono and sesquiterpenes the following new sesquiterpenes were identified: trans-humul-9(E)-en-2,6-dione (8); 4,5-seco-african-4,5-dione (9); 1,6-cis-and 1,6-trans-lippifolian-1α-o1-5-one (5) and (6) respectively; lippifoli-1(6)-en-4α-o1-5-one (7) and the sesquiterpenes 10 - 12 whose structures and conformations are discussed.  |l eng 
593 |a Inst. de Qca. Org., Fac. de Bqca Qca y Farmacia, Univ. Nac. de Tucumán, Ayacucho 491, Tucumán 4000, Argentina 
593 |a Depto de Qca. Org., Fac. de Ciencias Exactas y Naturales, Univ. de Buenos Aires, Pab. 2 Ciudad Universitaria, 1428, Buenos Aires, Argentina 
593 |a Departamento de Química, Centra de Investigación y de Estudios, Avanzados Instituto Politécnico Nacional, Apartado 14-740, México, D.F., 07000, Mexico 
690 1 0 |a ESSENTIAL OIL 
690 1 0 |a SESQUITERPENES 
690 1 0 |a STEREOCHEMISTRY 
690 1 0 |a STRUCTURE 
690 1 0 |a VERBENACEAE 
700 1 |a De Fenik, I.S. 
700 1 |a Catalán, C.A.N. 
700 1 |a Dartayet, G.H. 
700 1 |a Gros, E.G. 
700 1 |a Cerda-García-Rojas, C.M. 
700 1 |a Mora-Pérez, Y. 
700 1 |a Joseph-Nathan, P. 
773 0 |d International Society for Horticultural Science, 1999  |g v. 500  |h pp. 81-88  |p Acta Hortic.  |x 05677572  |z 9789066059917  |t Acta Horticulturae 
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