A simple enzymatic procedure for the synthesis of a hydroxylated polyester from glycerol and adipic acid

Lipase B from Candida antarctica catalyzed regioselectively the polyesterification of glycerol and adipic acid. UV-MALDI-TOF-MS analysis of the polymers shows low molecular weight polyesters (1314-1716) with very narrow polydispersities (1.0-1.2).

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Detalles Bibliográficos
Autor principal: Iglesias, L.E
Otros Autores: Fukuyama, Y., Nonami, H., Erra-Balsells, R., Baldessari, A.
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1999
Acceso en línea:Registro en Scopus
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Registro en la Biblioteca Digital
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030 |a BTECE 
100 1 |a Iglesias, L.E. 
245 1 2 |a A simple enzymatic procedure for the synthesis of a hydroxylated polyester from glycerol and adipic acid 
260 |c 1999 
270 1 0 |m Iglesias, L.E.; Centro de Estudios e Investigaciones, Universidad Nacional de Quilmes, Roque Saenz Pena 180, 1876 Bernal, Prov. de Buenos Aires, Argentina; email: alib@qo.fcen.uba.ar 
506 |2 openaire  |e Política editorial 
504 |a Chaudhary, A.K., Beckman, E.J., Russell, A.J., Enzymes for polyester synthesis (1996) Enzymes in Polymer Synthesis, , Gross RA, Kaplan DL, Swift G, eds. Ch. 2, Washington: ACS 
504 |a Dordick, J.S., (1992) Trends Biotech., 19, pp. 287-293 
504 |a Kaplan, D.L., Dordick, J., Gross, R.A., Swift, G., Enzymes in polymer science: An introduction (1996) Enzymes in Polymer Synthesis, , Gross RA, Kaplan DI, Swift G, eds. Ch. 1, Washington: ACS 
504 |a Kline, B.J., Beckman, E.J., Russell, A.J., (1998) J. Am. Chem. Soc., 120, pp. 9475-9480 
504 |a Kobayashi, S., Uyama, H., Enzymatic polymerization for synthesis of polyesters and polyaromatics (1996) Enzymes in Polymer Synthesis, , Gross RA, Kaplan DL, Swift G, eds. Ch. 3, Washington: ACS 
504 |a Margolin, A.L., Crenne, J.-Y., Klibanov, A.M., (1987) Tetrahedron Lett., 28, pp. 1607-1610 
504 |a Nonami, H., Fukui, S., Erra-Balsells, R., (1997) J. Mass Spectrom., 32, pp. 287-296 
504 |a Nonami, H., Tanaka, K., Fukuyama, Y., Erra-Balsells, R., (1998) Rapid Commun. Mass Spect., 12, pp. 285-296 
504 |a Park, H.G., Chang, H.N., Dordick, J.S., (1994) Biocatalysis, 11, pp. 263-271 
504 |a (1992) Ulmann's Encyclopedia of Industrial Chemistry, A21, p. 227. , Weinheim, Germany: VCH 
504 |a Wallace, J.S., Morrow, C.J., (1989) J. Polym. Sci. Part A: Polym.Chem., 27, pp. 2553-2567 
520 3 |a Lipase B from Candida antarctica catalyzed regioselectively the polyesterification of glycerol and adipic acid. UV-MALDI-TOF-MS analysis of the polymers shows low molecular weight polyesters (1314-1716) with very narrow polydispersities (1.0-1.2).  |l eng 
536 |a Detalles de la financiación: Universidad de Buenos Aires 
536 |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas 
536 |a Detalles de la financiación: We thank CONICET and UBA for partial financial support. REB and AB are research members of CONICET.UV-MALDI-TOF-MS experiments were performed as part of the Academic Agreement between REB (FCEyN-UBA, Argentina) and HN (CA-EU, Japan) with the facilities of the High Resolution Liquid Chromatography-integrated Mass Spectrometry System of the United Graduated School of Agricultural Sciences (EU, Japan). 
593 |a Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, 1428 Buenos Aires, Argentina 
593 |a Plant Biophysics/Biochemistry Research Laboratory, College of Agriculture, Ehime University, 3-5-7 Tarumi, Matsuyama 790-8566, Japan 
593 |a Centra de Estudios e Investigaciones, Universidad Nacional de Quilmes, Roque Sáenz Peña 180, 1876 Bernal, Prov. de Buenos Aires, Argentina 
690 1 0 |a ENZYMATIC POLYMERIZATION 
690 1 0 |a LIPASE 
690 1 0 |a REGIOSELECTIVITY 
690 1 0 |a UV-MALDI-TOF-MS 
690 1 0 |a ADIPIC ACID 
690 1 0 |a CATALYSIS 
690 1 0 |a ENZYMIC ESTERIFICATION 
690 1 0 |a GLYCEROL 
690 1 0 |a HYDROXYLATION 
690 1 0 |a LIPASE B 
690 1 0 |a MASS SPECTROMETRY 
690 1 0 |a MOLECULAR WEIGHT 
690 1 0 |a POLYMER 
690 1 0 |a CANDIDA ANTARCTICA 
700 1 |a Fukuyama, Y. 
700 1 |a Nonami, H. 
700 1 |a Erra-Balsells, R. 
700 1 |a Baldessari, A. 
773 0 |d 1999  |g v. 13  |h pp. 923-926  |k n. 12  |p Biotechnol. Tech.  |x 0951208X  |w (AR-BaUEN)CENRE-1441  |t Biotechnology Techniques 
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856 4 0 |u https://doi.org/10.1023/A:1008958212814  |y DOI 
856 4 0 |u https://hdl.handle.net/20.500.12110/paper_0951208X_v13_n12_p923_Iglesias  |y Handle 
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