The photophysics of nitrocarbazoles studied by using spectroscopic, photoacoustic and luminescence techniques

The photophysical behaviour of 1-nitrocarbazol and 3-nitrocarbazol in different organic solvents has been studied by using spectroscopic, luminescence and photoacoustic techniques. Absorption spectra and triplet state transient spectra were recorded and formation quantum yields and lifetimes determi...

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Detalles Bibliográficos
Autor principal: Mesaros, M.
Otros Autores: Bonesi, S.M, Ponce, M.A, Erra-Balsells, R., Bilmes, Gabriel Mario
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2003
Acceso en línea:Registro en Scopus
DOI
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Registro en la Biblioteca Digital
Aporte de:Registro referencial: Solicitar el recurso aquí
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100 1 |a Mesaros, M. 
245 1 4 |a The photophysics of nitrocarbazoles studied by using spectroscopic, photoacoustic and luminescence techniques 
260 |c 2003 
270 1 0 |m Erra-Balsells, R.; Departamento de Química Orgánica, Facultadde Ciencias Exactas y Naturales, Universidadde Buenos Aires, (1428) Buenos Aires, Argentina 
504 |a Biondic, M.C., Erra-Balsells, R., Photochemical behavior of β-carbolines. Part 4. Acid-base equilibria in the ground and excited states in organic media (1997) J. Chem. Soc., Perkin Trans., 2, pp. 1323-1328 
504 |a Biondic, M.C., Erra-Balsells, R., Photochemical behaviour of p-carbolincs. Part 5. Ground and excited state interactions between nor-harmane and harmane with alcohols and ethers (1998) J. Chem. Res., (S), pp. 114-115 
504 |a Bonesi, S.M., Erra-Balsells, R., Product study of the photolysis of N-Acetyl carbazole in ethanol and in dichloromethane solution. I (1991) J. Photochem. Photobiol. A: Chem., 56, pp. 55-72 
504 |a Bonesi, S.M., Erra-Balsells, R., Outer-Sphere electron transfer from carbazoles to halomethanes. Reduction Potentials of halomethanes measured by fluorescence quenching experiments (2000) J. Chem. Soc., Perkin Trans., 2, pp. 1583-1595 
504 |a Nonami, H., Fukui, S., Erra-Balsells, R., β-carboline alkaloids as matrices for matrix-assisted ultraviolet laser desorption time-of-flight mass spectrometry of proteins and sulfated oligosaccharides: A comparative study using phenylcarbonyl compounds, carbazoles and classical matrices (1997) J. Mass Spectrom., 32, pp. 287-296 
504 |a Nonami, H., Tanaka, K., Fukuyama, Y., Erra-Balsells, R., β-carboline alkaloids as matrices for UV-Matrix-assisted laser desorption/ionization time-of-flight mass spectrometry in positive and negative ion Modes. Analysis of proteins of high molecular mass, and of cyclic and acyclic olicosaccharides (1998) Rapid Commun. Mass Spectrom., 12, pp. 285-296 
504 |a Bonesi, S.M., Erra-Balsells, R., Electronic spectroscopy of carbazole and N- and C-substituted carbazole in homogeneous media and in solid matrix (2001) J. Lumin., 93, pp. 51-74 
504 |a Bonesi, S.M., Erra-Balsells, R., Electronic spectroscopy of N- and C-substituted chlorocarbazoles in homogeneous media and in solid matrix (2002) J. Lumin., 97, pp. 83-101 
504 |a Turro, N.J., (1978) Modern Molecular Photochemistry, , The Benjamin Cummings Publishing Company, Inc., CA 
504 |a Birks, J.B., (1970) Photophysics of Aromatic Molecules, , Wiley Interscience, New York 
504 |a Ponce, M.A., Erra-Balsells, R., Synthesis and isolation of nitro-β-carbolines obtained by nitration of -carboline alkaloids (2001) J. Heterocycl. Chem., 38, pp. 1071-1082 
504 |a Perrin, D.D., Amarego, W.L.F., (1988) Purification of Laboratory Chemicals, , Pergamon Press, New York, 3rd edn 
504 |a Van Haver, P., Viaene, L., Van Der Auweraes, M., De Schyver, F.C., References for laser-induced optoacoustic spectroscopy usins UV excitation (1990) J. Photochem. Photobiol, A: Chem., 63, pp. 265-277 
504 |a Malaga, N., Toriashi, Y., Ezumi, K., Electronic structure of carbazole and indole, and the solvent effects on the electronic spectra (1964) Theor. Chim. Acta, 2, pp. 158-167 
504 |a Huber, J.R., Adams, J.E., Effect of the molecular geometry on the electronic structure of aromatic amines. Diphenylamine, iminodibenzyl, acridan and carbazole (1974) Bcr. Bunsenges. Phys. Chem., 78, pp. 217-233 
504 |a Chakravorty, S.C., Ganguly, S.C., Polarized absorption spectra of carbazole single crystal (1970) J. Chem. Phys., 52, pp. 2760-2762 
504 |a Mc Glyn, S.P., Azumi, T., Kinoshita, M., (1969) Molecular Spectroscopy of the Triplet State, 6, p. 251. , Prentice - Hall Inc., Englewood Cliff, New York 
504 |a Murov, S.L., Carmicheal, I., Hug, G.L., (1993) Handbook of Photochemistry, , Marcel Dekker Inc., New York, 2nd edn 
504 |a Snadros, K., Transfer of triplet state energy in fluid solutions (1969) Acta Chem. Scand., 23, pp. 2815-2829 
504 |a Terazima, M., Azumi, T., A time-resolved photoacoustic method widht pulsed laser excitation in the condensed phase: The relation between signal intensity and decay-rate constant (1990) Bull. Chem. Soc. Jpn., 63, pp. 741-745 
504 |a Marti, C., Jurgens, O., Cuenca, O., Casals, M., Nonell, S., Aromatic ketones as standards for singlet molecular oxygen photosensitization. Time resolved photoacoustic and near-IR emission studies (1996) J. Photochem. Photobiol., A: Chem., 97, pp. 11-18 
504 |a Small, J.R., Libertini, L.J., Small, E.W., Analysis of photoacoustic waveforms using the nonlinear least squares method (1992) Biophys. Chem., 42, pp. 29-48 
504 |a Braslavsky, S.E., Heibel, G.E., Time resolved photothermal and photoacoustic methods applied to photoinduced processes in solution (1992) Client. Rev., 92, pp. 1381-1410 
504 |a Trotter, W., Testa, A.C., Photorcduction of 1-nitronaphthalene by protonation in the excited state (1970) J. Phys. Chem., 74, pp. 845-847 
504 |a Cu, A., Testa, A.C., Photochemistry of the nitro group in aromatic heterocyclic molecules (1975) J. Phys. Chem., 79, pp. 644-646 
506 |2 openaire  |e Política editorial 
520 3 |a The photophysical behaviour of 1-nitrocarbazol and 3-nitrocarbazol in different organic solvents has been studied by using spectroscopic, luminescence and photoacoustic techniques. Absorption spectra and triplet state transient spectra were recorded and formation quantum yields and lifetimes determined. Phosphorescence emission at 77 K and laser induced luminescence in acetonitrile solution at 298 K for the nitrocarbazoles were studied. Results are discussed in terms of the optimized structure of 1-nitrocarbazole and 3-nitrocarbazole and compared with that of carbazole. The nitro group attached to the carbazole moiety induces important changes in the photophysical behavior of those compounds. © The Royal Society of Chemistry and Owner Societies 2003.  |l eng 
593 |a Centro de Investigaciones Opticas (CONICET-CIC), Casilla de Correo 124, (1900) La Plata, Argentina 
593 |a Departamento de Química Orgánica, Facultadde Ciencias Exactas y Naturales, Universidadde Buenos Aires, (1428) Buenos Aires, Argentina 
593 |a Centro de Investigaciones Opticas (CONICET-CIC), Universidad Nacional de la Plata, Casilla de Correo 124, (1900) La Plata, Argentina 
690 1 0 |a 1 NITROCARBAZOLE 
690 1 0 |a 3 NITROCARBAZOLE 
690 1 0 |a CARBAZOLE DERIVATIVE 
690 1 0 |a UNCLASSIFIED DRUG 
690 1 0 |a ABSORPTION 
690 1 0 |a ACOUSTICS 
690 1 0 |a ARTICLE 
690 1 0 |a CHEMICAL ANALYSIS 
690 1 0 |a LUMINESCENCE 
690 1 0 |a PHOTOACOUSTICS 
690 1 0 |a PHOTOCHEMISTRY 
690 1 0 |a PHYSICAL CHEMISTRY 
690 1 0 |a PRIORITY JOURNAL 
690 1 0 |a QUANTUM CHEMISTRY 
690 1 0 |a SPECTROSCOPY 
700 1 |a Bonesi, S.M. 
700 1 |a Ponce, M.A. 
700 1 |a Erra-Balsells, R. 
700 1 |a Bilmes, Gabriel Mario 
773 0 |d 2003  |g v. 2  |h pp. 808-816  |k n. 7  |p Photochem. Photobiol. Sci.  |x 1474905X  |t Photochemical and Photobiological Sciences 
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