Mixed-valent diruthenium (II,III) aliphatic carboxylates: Columnar mesophases in dodecylsulfate and octylsulfonate derivatives
Two series of polymeric mixed-valent diruthenium (II,III) aliphatic carboxylates of formula Ru2[O2C(CH2) n-2CH3]4X (where X=dodecylsulfate (DOS) anion and n=8, 9, 16 and 18, or X=octylsulfonate (OS) anion and n=8, 10, 12, 14 and 18) were synthesized and characterized. Their liquid crystalline proper...
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| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
2004
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
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| LEADER | 05198caa a22007097a 4500 | ||
|---|---|---|---|
| 001 | PAPER-21216 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518205239.0 | ||
| 008 | 190411s2004 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-3242687160 | |
| 024 | 7 | |2 cas |a dodecyl sulfate, 151-41-7; octane, 111-65-9; ruthenium, 7440-18-8 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a LICRE | ||
| 100 | 1 | |a Chaia, Z. | |
| 245 | 1 | 0 | |a Mixed-valent diruthenium (II,III) aliphatic carboxylates: Columnar mesophases in dodecylsulfate and octylsulfonate derivatives |
| 260 | |c 2004 | ||
| 270 | 1 | 0 | |m Cukiernik, F.D.; INQUIMAE, Departamento de Quimica Inorganica, Universidad de Buenos Aires, C1428EHA Buenos Aires, Argentina; email: fcukiern@ungs.edu.ar |
| 506 | |2 openaire |e Política editorial | ||
| 504 | |a Aquino, M.A.S., (1998) Coord. Chem. Rev., 170, p. 141 | ||
| 504 | |a Cukiernik, F.D., Maldivi, P., Giroud-Godquin, A.M., Marchon, J.C., Ibn-Elhaj, M., Guillon, D., Skoulios, A., (1991) Liq. Cryst., 9, p. 903 | ||
| 504 | |a Cukiernik, F.D., Ibn-Elhaj, M., Chaia, Z., Marchon, J.C., Giroud-Godquin, A.M., Guillon, D., Skoulios, A., Maldivi, P., (1998) Chem. Mater., 10, p. 83 | ||
| 504 | |a Chaia, Z., Heinrich, B., Cukiernik, F.D., Guillon, D., (1999) Mol. Cryst. Liq. Cryst., 330, p. 213 | ||
| 504 | |a Guillon, D., (1999) Struct. Bonding (Berlin), 95, p. 42 | ||
| 504 | |a Caplan, J.F., Murphy, C.A., Swansburg, S., Lemieux, R.P., Cameron, T.S., Aquino, M.A.S., (1998) Can. J. Chem., 76, p. 1520 | ||
| 504 | |a Zelcer, A., Chaia, Z., Cukiernik, F.D., Castellano, E.E., Piro, O.E., (2002) Acta Cryst., C58, pp. m144 | ||
| 504 | |a Nakamoto, K., (1986) Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th Edn, , New York: John Wiley | ||
| 504 | |a Guillon, D., Skoulios, A., Benattar, J.J., (1986) J. Phys., 47, p. 133 | ||
| 520 | 3 | |a Two series of polymeric mixed-valent diruthenium (II,III) aliphatic carboxylates of formula Ru2[O2C(CH2) n-2CH3]4X (where X=dodecylsulfate (DOS) anion and n=8, 9, 16 and 18, or X=octylsulfonate (OS) anion and n=8, 10, 12, 14 and 18) were synthesized and characterized. Their liquid crystalline properties and crystalline (Cr) structures were analysed; the Cr phases are lamellar in all cases. For long chain DOS derivatives (n=16 and 18) hexagonal and rectangular columnar mesophases (Colh and Colr) with melting temperatures close to 140°C were observed. For long chain OS derivatives (n ≥ 10) a Colh mesophase was observed, with melting temperatures between 140 and 190°C. |l eng | |
| 536 | |a Detalles de la financiación: Universidad de Buenos Aires, EX117, AX27 | ||
| 536 | |a Detalles de la financiación: Fundación Antorchas | ||
| 536 | |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica, 546, PEI 121/98, A97E08 | ||
| 536 | |a Detalles de la financiación: We wish to thank Drs P. Maldivi and J.C. Marchon (CEA/Grenoble) for help at the beginning of this work, as well as B. Heinrich (GMO-IPCMS) for help during the X-ray diffraction investigations. Financial Support from the University of Buenos Aires (EX117 and AX27), Fundación Antorchas, ANPCyT (546), Conicet (PEI 121/98) and Ecos-Secyt (grant A97E08 for international cooperation) is acknowledged. Z.D.C. and M.R. thank CONICET for doctoral fellowships. A.Z. thanks UBA for a student fellowship. F.D.C. is a member of the scientific staff of CONICET. | ||
| 593 | |a INQUIMAE, Departamento de Quimica Inorganica, Universidad de Buenos Aires, C1428EHA Buenos Aires, Argentina | ||
| 593 | |a Inst. Phys./Chim. Mat. de Strasbourg, Grp. des Mat. Organiques (GMO-IPCMS), 23 Rue de Loess, 67034 Strasbourg Cedex 2, France | ||
| 593 | |a Instituto de Ciencias, Univ. Nacional de General Sarmiento, J. M. Gutierrez 1150, Los Polvorines, Prov. Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a ALIPHATIC COMPOUND |
| 690 | 1 | 0 | |a CARBOXYLIC ACID DERIVATIVE |
| 690 | 1 | 0 | |a DODECYL SULFATE |
| 690 | 1 | 0 | |a OCTANE |
| 690 | 1 | 0 | |a POLYMER |
| 690 | 1 | 0 | |a RUTHENIUM |
| 690 | 1 | 0 | |a SULFONIC ACID DERIVATIVE |
| 690 | 1 | 0 | |a ARTICLE |
| 690 | 1 | 0 | |a CRYSTAL STRUCTURE |
| 690 | 1 | 0 | |a LIQUID CRYSTAL |
| 690 | 1 | 0 | |a MELTING POINT |
| 690 | 1 | 0 | |a MESOPHASE |
| 690 | 1 | 0 | |a PHYSICAL CHEMISTRY |
| 690 | 1 | 0 | |a SYNTHESIS |
| 700 | 1 | |a Zelcer, A. | |
| 700 | 1 | |a Donnio, B. | |
| 700 | 1 | |a Rusjan, M. | |
| 700 | 1 | |a Cukiernik, F.D. | |
| 700 | 1 | |a Guillon, D. | |
| 773 | 0 | |d 2004 |g v. 31 |h pp. 1019-1025 |k n. 7 |p Liq. Cryst. |x 02678292 |w (AR-BaUEN)CENRE-5971 |t Liquid Crystals | |
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| 856 | 4 | 0 | |u https://doi.org/10.1080/02678290410001713333 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_02678292_v31_n7_p1019_Chaia |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02678292_v31_n7_p1019_Chaia |y Registro en la Biblioteca Digital |
| 961 | |a paper_02678292_v31_n7_p1019_Chaia |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 999 | |c 82169 | ||