Evaluation of sorption and desorption characteristics of cadmium, lead and zinc on amberlite IRC-718 iminodiacetate chelating ion exchanger

A chelating type ion exchange resin (Amberlite IRC-718), containing iminodiacetate groups as active sites, has been characterized regarding the sorption and subsequent elution of Cd, Zn and Pb, aiming to metal preconcentration from solution samples of different origins. The methodology developed is...

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Autor principal: Malla, M.E
Otros Autores: Alvarez, M.B, Batistoni, D.A
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: Elsevier 2002
Materias:
PH
Acceso en línea:Registro en Scopus
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024 7 |2 scopus  |a 2-s2.0-0037118098 
024 7 |2 cas  |a cadmium, 22537-48-0, 7440-43-9; diglycine, 142-73-4; lead, 7439-92-1, 13966-28-4; polacrilin, 50602-21-6, 54182-62-6, 80892-32-6, 9002-23-7, 9002-29-3, 9014-38-4, 9042-11-9, 9079-25-8; water, 7732-18-5; zinc, 7440-66-6, 14378-32-6 
040 |a Scopus  |b spa  |c AR-BaUEN  |d AR-BaUEN 
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100 1 |a Malla, M.E. 
245 1 0 |a Evaluation of sorption and desorption characteristics of cadmium, lead and zinc on amberlite IRC-718 iminodiacetate chelating ion exchanger 
260 |b Elsevier  |c 2002 
270 1 0 |m Batistoni, D.A.; Chemistry Unit, Constituyentes Atomic Center, Comn. Nacional de Energia Atomica, Avenida General Paz 1499, (1650) San Martin, Buenos Aires, Argentina; email: batiston@cnea.gov.ar 
506 |2 openaire  |e Política editorial 
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504 |a Walton, H.P., (1964) Principles and Methods of Chemical Analysis, second ed., p. 155. , Prentice Hall, New York 
504 |a Hashemi, P., Olin, Å., (1997) Talanta, 44, p. 1037 
504 |a Knežević, S., Milačič, R., Veber, M., (1998) Fresenius J. Anal. Chem., 362, p. 162 
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504 |a Paulson, A., (1986) Anal. Chem., 58, p. 183 
504 |a Greenwood, N.N., Earnshaw, A., (1997) Chemistry of the Elements, second ed., , Butterworth-Heinemann, Oxford 
504 |a Sylverstein, R.M., Clayton Bassler, G., Morrill, T.C., (1991) Spectrometric Identification of Organic Compounds, fifth ed., , Wiley, New York 
504 |a Alvarez, M.B., Malla, M.E., Batistoni, D.A., (2001) Fresenius J. Anal. Chem., 369, p. 81 
520 3 |a A chelating type ion exchange resin (Amberlite IRC-718), containing iminodiacetate groups as active sites, has been characterized regarding the sorption and subsequent elution of Cd, Zn and Pb, aiming to metal preconcentration from solution samples of different origins. The methodology developed is based on off-line operation employing mini columns made of the sorbent. The eluted metals were determined by flame atomic absorption spectrometry. The effect of column conditioning, influent pH and flow rate during the sorption step, and the nature of the acid medium employed for desorption of the retained metals were investigated. Working (breakthrough) and total capacities were measured under dynamic operating conditions and the results compared with those obtained with Chelex-100, a resin extensively employed for analytical preconcentration. Structural information on the complexation of metals by the chelating groups was obtained by Fourier Transform infrared spectrometry. The analytical response of the Amberlite sorbent was assessed for the analysis of water samples and digestates of marine sediments. © 2002 Elsevier Science B.V. All rights reserved.  |l eng 
536 |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica, PICT-06-00000-0354 
536 |a Detalles de la financiación: Universidad Nacional del Sur, 24M052, 068 
536 |a Detalles de la financiación: 95-Q-02-01, 02–03 
536 |a Detalles de la financiación: The authors are indebted to Myriam Crespo (CERZUS, CONICET) for her collaboration in performing the atomic absorption analyses, to Mireille Perec (INQUIMAE) for obtaining and helping in the interpretation of the FT-IR spectra, and to Marı́a dos Santos Afonso (INQUIMAE) for performing the resin microanalyses. This work was carried out as part of CNEA-CAC Projects 95-Q-02-01 and 02–03. Financial support was provided by Agencia Nacional de Promoción Cientı́fica y Tecnológica (Project PICT-06-00000-0354) and SGCYT, Universidad Nacional del Sur (Projects 24M052 and 068). 
593 |a Department of Chemistry and Chemical Engineering, Universidad Nacional del Sur, Provincia de Buenos Aires, Argentina 
593 |a Chemistry Unit, Constituyentes Atomic Center, Comisión Nacional De Energía Atómica, Avenida General Paz 1499, Provincia de Buenos Aires, Argentina 
593 |a INQUIMAE, School of Sciences, Universidad De Buenos Aires, Buenos Aires, Argentina 
690 1 0 |a ATOMIC ABSORPTION 
690 1 0 |a CADMIUM 
690 1 0 |a CHELATING RESIN 
690 1 0 |a ION EXCHANGE 
690 1 0 |a LEAD 
690 1 0 |a ZINC 
690 1 0 |a CADMIUM 
690 1 0 |a CHELATION 
690 1 0 |a COMPLEXATION 
690 1 0 |a DESORPTION 
690 1 0 |a FOURIER TRANSFORM INFRARED SPECTROSCOPY 
690 1 0 |a LEAD 
690 1 0 |a PH EFFECTS 
690 1 0 |a SPECTROMETRY 
690 1 0 |a ZINC 
690 1 0 |a ATOMIC ABSORPTION SPECTROMETRY 
690 1 0 |a ION EXCHANGE RESINS 
690 1 0 |a CADMIUM 
690 1 0 |a CHELATING AGENT 
690 1 0 |a DIGLYCINE 
690 1 0 |a LEAD 
690 1 0 |a METAL COMPLEX 
690 1 0 |a POLACRILIN 
690 1 0 |a RESIN 
690 1 0 |a SORBENT 
690 1 0 |a WATER 
690 1 0 |a ZINC 
690 1 0 |a ABSORPTION 
690 1 0 |a ARTICLE 
690 1 0 |a ATOMIC ABSORPTION 
690 1 0 |a ATOMIC ABSORPTION SPECTROMETRY 
690 1 0 |a CHEMICAL STRUCTURE 
690 1 0 |a COMPLEX FORMATION 
690 1 0 |a DESORPTION 
690 1 0 |a ELUTION 
690 1 0 |a FLOW RATE 
690 1 0 |a FOURIER TRANSFORMATION 
690 1 0 |a INFRARED SPECTROMETRY 
690 1 0 |a INSTRUMENTAL CONDITIONING 
690 1 0 |a ION EXCHANGE 
690 1 0 |a MEASUREMENT 
690 1 0 |a METHODOLOGY 
690 1 0 |a SEDIMENT 
690 1 0 |a WATER SAMPLING 
650 1 7 |2 spines  |a PH 
700 1 |a Alvarez, M.B. 
700 1 |a Batistoni, D.A. 
773 0 |d Elsevier, 2002  |g v. 57  |h pp. 277-287  |k n. 2  |p Talanta  |x 00399140  |w (AR-BaUEN)CENRE-224  |t Talanta 
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