Porphyrin-induced protein structural alterations of heme enzymes

Some alterations in the protein structure of d-aminolevulinic acid dehydratase (ALA-D) and porphobilinogen deaminase (PBG-D) induced by uroporphyrin (URO) and prototoporphyrin (PROTO) have been observed previously. To obtain further evidence of these phenomena, the absorption and fluorescence spectr...

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Detalles Bibliográficos
Autor principal: Afonso, S.G
Otros Autores: De Salamanca, R.E, Batlle, A.M.D.C
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1997
Acceso en línea:Registro en Scopus
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Registro en la Biblioteca Digital
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LEADER 11186caa a22010817a 4500
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005 20230518205126.0
008 190411s1997 xx ||||fo|||| 00| 0 eng|d
024 7 |2 scopus  |a 2-s2.0-0342601352 
024 7 |2 cas  |a Amino Acids; Heme, 14875-96-8; Hydroxymethylbilane Synthase, EC 2.5.1.61; Porphobilinogen Synthase, EC 4.2.1.24; Porphyrins; protoporphyrin IX, 553-12-8; Protoporphyrins; Sulfhydryl Compounds; uroporphyrin I, 607-14-7; Uroporphyrins 
040 |a Scopus  |b spa  |c AR-BaUEN  |d AR-BaUEN 
030 |a IJBBF 
100 1 |a Afonso, S.G. 
245 1 0 |a Porphyrin-induced protein structural alterations of heme enzymes 
260 |c 1997 
270 1 0 |m Enriquez De Salamanca, R.Francisco Gervas 9, 28020 Madrid, Spain 
506 |2 openaire  |e Política editorial 
504 |a Afonso, S., Chinarro, S., Muñoz, J., Salamanca, R.E., Batlle, A., Light-dependent and light-independent inactivation of red cell porphobilinogenase by type I and III porphyrins (1987) Bolletino Istituto Dermatologico San Gallicano, 13, pp. 35-40 
504 |a Afonso, S., Chinarro, S., Muñoz, J., Salamanca, R.E., Batlle, A., Photodynamic and non-photodynamic action of several porphyrins on the activity of some heme-enzymes (1990) Journal of Enzyme Inhibition, 3, pp. 303-310 
504 |a Afonso, S., Chinarro, S., Salamanca, R.E., Batlle, A., Further evidence on the photodynamic and the novel non-photodynamic inactivation of uroporphyrinogen decarboxylase by uroporphyrin I (1991) Journal of Enzyme Inhibition, 5, pp. 225-233 
504 |a Afonso, S., Chinarro, S., Salamanca, R.E., Batlle, A., δ-aminolevulinic acid dehydratase inactivation by uroporphyrin i in light and darkness (1994) International Journal of Biochemistry, 26, pp. 255-258 
504 |a Afonso, S.G., Polo, C.F., Enríquez de Salamanca, R., Batlle, A., Mechanistic studies on URO I-induced enzyme photoinactivation (1996) International Journal of Biochemistry and Cell Biology, 28, pp. 415-420 
504 |a Afonso, S., Salamanca, R.E., Batlle, A., Folding and unfolding of δ-aminolevulinic acid dehydratase and porphobilinogen deaminase induced by Uro and Protoporphyrin (1997) International Journal of Biochemistry and Cell Biology, 29, pp. 493-503 
504 |a Batlle, A.M.D.C., Salamanca, R.E., Chinarro, S., Afonso, S., Stella, A.M., Photodynamic inactivation of red cell uroporphyrinogen decarboxylase by porphyrins (1986) International Journal of Biochemistry, 18, pp. 143-147 
504 |a Bodaness, S.R., The nonphotosensitized potentiation by the photosensitizer hematoporphyrin of the horse-radish peroxidase-catalyzed hydrogen peroxide-mediated oxidation of NADPH to NADP + (1984) Biochemical and Biophysical Research Communications, 118, pp. 191-197 
504 |a Brun, A., Sandberg, S., Photodynamic release of proto-porphyrin from intact erythrocytes in erythropoietic protoporphyrin: The effect of small repetitive light doses (1985) Photochemistry and Photobiology, 41, pp. 535-541 
504 |a Chinarro, S., Afonso, S., Stella, A.M., Salamanca, R.E., Battle, A., Acción fotodinámica de las porfirinas sobre la actividad de la uroporfirinogeno decarboxilasa eritrocitaria (1985) Biometrica, 10, pp. 75-80 
504 |a Dubbelman, T.M.A.R., De Goeij, A.F.P.M., Van Steveninck, J., Photodynamic effect of protoporphyrin on human erythrocytes. Nature of the cross-linking of membrane proteins (1978) Biochimica et Biophysica Acta, 511, pp. 141-151 
504 |a Firey, P.A., Rodgers, M.J.A., Photochemical properties of erythrocyte ghosts containing porphyrin (1988) Photochemistry and Photobiology, 47, pp. 615-619 
504 |a Habeeb, A.F.S., Reaction of protein sulfhydryl groups with Ellman's reagent (1972) Methods in Enzymology, 25, pp. 457-464. , Edited by Colowick S. and Kaplan N., Academic Press, New York 
504 |a Ignarro, L.J., Wood, K.S., Wolin, M.S., Activation of purified soluble guanylate cyclase by protoporphyrin IX (1982) Proceedings of the National Academy of Sciences U.S.A., 70, pp. 2870-2873 
504 |a Lim, H.W., Gigli, I., Wasserman, S.I., Differential effects of protoporphyrin and uroporphyrin on murine mast cells (1987) Journal of Investigative Dermatology, 88, pp. 281-286 
504 |a Lowry, O.H., Rosebrough, N.J., Farr, A.O., Randall, R.J., Protein measurement with the folin phenol reagent (1951) Journal of Biological Chemistry, 193, pp. 265-275 
504 |a Magnus, I., Porter, A.D., Rimington, C., The action spectrum for skin lesions in porphyria cutanea tarda (1959) Lancet, 1, pp. 912-914 
504 |a Moan, J., The photochemical yield of singlet oxygen from porphyrins in different states of aggregation (1984) Photochemistry and Photobiology, 39, pp. 445-449 
504 |a Sandberg, S., Brun, A., Light-induced protoporphyrin release from erythrocytes in erythropoietic protoporphyria (1982) Journal of Clinical Investigation, 70, pp. 693-698 
504 |a Spikes, J.D., Porphyrins and related compounds as photodynamic sensitizers (1975) Annals of the New York Academy of Science, 244, pp. 496-508 
504 |a Spikes, J.D., A preliminary comparisson of the photosensitizing properties of porphyrins in aqueous solution and liposomal systems (1983) Advances in Experimental Medicine and Biology, 60, pp. 180-192 
504 |a Udenfriend, S., Stein, S., Bohlen, P., Dalrman, W., Fluorescamine: A reagent for assay of aminoacids, peptides, proteins and primary amines in the picomole range (1972) Science, 178, pp. 871-872 
504 |a Van Steveninck, J., Dubbelman, T.M.A.R., Verweij, H., Photodynamic membrane damage (1983) Porphyrin Photosensitization, pp. 2227-2240. , Plenum Press, New York 
504 |a Van Steveninck, J., Boegheim, J.P.J., Dubbelman, T.M.A.R., Van der Zee, J., The influence of porphyrins on iron-catalyzed generation of hydroxyl radicals (1988) Biochemical Journal, 250, pp. 197-201 
504 |a Varigos, G., Schiltz, J.R., Bickers, D.R., Uroporphyrin I stimulation of collagen biosynthesis in human skin fibroblasts (1982) Journal of Clinical Investigation, 69, pp. 129-135 
504 |a Verweij, H., Van Steveninck, J., Model studies on photodynamic cross-linking (1982) Photochemistry and Photobiology, 35, pp. 265-267 
504 |a Verweij, H., Dubbelman, T.M.A.R., Van Steveninck, J., Photodynamic protein cross-linking (1981) Biochimica et Biophysica Acta, 647, pp. 87-94 
504 |a Vincent, S.H., Holeman, B., Cully, B.C., Müller-Eberhard, U., Porphyrin-induced photodynamic cross-linking of hepatic heme-binding proteins (1986) Life Sciences, 38, pp. 365-372 
520 3 |a Some alterations in the protein structure of d-aminolevulinic acid dehydratase (ALA-D) and porphobilinogen deaminase (PBG-D) induced by uroporphyrin (URO) and prototoporphyrin (PROTO) have been observed previously. To obtain further evidence of these phenomena, the absorption and fluorescence spectra of ALA-D and PBG-D and the total protein content of sulfhydryl and free amino groups were analyzed after exposure of the enzymes to URO I and PROTO IX. ALA-D and PBG-D were partially purified from bovine liver and exposed to URO I or PROTO IX, both in the dark and under UV light. All experiments were performed in the enzyme solutions after removing the porphyrins. Absorbance spectra changes in the region of 220-300 nm were registered, indicating the interaction of the porphyrins with the molecular structure of the enzymes. The main changes in the fluorescence spectra were observed in the spectral region of 555 nm, and only slight modifications in the spectral region of 340-360 nm; moreover, alterations were stronger upon UV irradiation and in the presence of URO P when compared with darkness and PROTO IX. Variations in total SH groups would suggest the formation of disulfur bridges induced by URO I and the rupture of some SS groups induced by PROTO IX. The effect of porphyrins on free amino groups would reflect a combination of cross-linking and fragmentation of proteins. Structural changes were observed when the enzymes were exposed to the porphyrin both in the dark or under UV light; however, they were stronger in tile latter condition. These results suggest that porphyrins per se could act directly on the protein structure and that this action would be enhanced upon UV irradiation.  |l eng 
536 |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas, 93/112 
536 |a Detalles de la financiación: Directorate-General XII, Science, Research, and Development 
536 |a Detalles de la financiación: Acknowledgements-Susana Afonso thanks the Directorate General for Science, Research and Development at the Commission of the European Communities, Belgium, for a post-doctoral fellowship. This work was supported by grants from the CONICET, Argentine and FISss (93/112) from Spain. A. Batlle is also grateful to the Ministerio de Educacibn y Ciencia (MEC), Spain, for special help. 
593 |a Ctro. de Invest. Sobre Porfirinas P., Fac. de Cie. Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina 
593 |a Unidad de Porfirias, Hospital Universitario 12 de Octubre, Universidad Complutense de Madrid, Madrid, Spain 
593 |a Francisco Gervas, 9 11o A, 28020 Madrid, Spain 
690 1 0 |a ENZGME STRUCTURE 
690 1 0 |a MOLECULAR ALTERATIONS 
690 1 0 |a PHOTODYNAMIC ACTION 
690 1 0 |a PORPHYRINS 
690 1 0 |a AMINOLEVULINIC ACID 
690 1 0 |a HEME 
690 1 0 |a PORPHYRIN 
690 1 0 |a PROTOPORPHYRIN 
690 1 0 |a ARTICLE 
690 1 0 |a CHEMICAL STRUCTURE 
690 1 0 |a CONTROLLED STUDY 
690 1 0 |a ENZYME STRUCTURE 
690 1 0 |a NONHUMAN 
690 1 0 |a PHOTODYNAMICS 
690 1 0 |a PROTEIN STRUCTURE 
690 1 0 |a AMINO ACIDS 
690 1 0 |a ANIMALS 
690 1 0 |a CATTLE 
690 1 0 |a HEME 
690 1 0 |a HYDROXYMETHYLBILANE SYNTHASE 
690 1 0 |a LIVER 
690 1 0 |a PORPHOBILINOGEN SYNTHASE 
690 1 0 |a PORPHYRINS 
690 1 0 |a PROTOPORPHYRINS 
690 1 0 |a SPECTROMETRY, FLUORESCENCE 
690 1 0 |a SPECTROPHOTOMETRY 
690 1 0 |a SULFHYDRYL COMPOUNDS 
690 1 0 |a ULTRAVIOLET RAYS 
690 1 0 |a UROPORPHYRINS 
690 1 0 |a BOVINAE 
700 1 |a De Salamanca, R.E. 
700 1 |a Batlle, A.M.D.C. 
773 0 |d 1997  |g v. 29  |h pp. 1113-1121  |k n. 8-9  |p INT. J. BIOCHEM. CELL BIOL.  |x 13572725  |w (AR-BaUEN)CENRE-5218  |t International Journal of Biochemistry and Cell Biology 
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