The crystal and molecular structure of sodium pentacyanoammineferrate(II) heptahydrate. Role of intermolecular hydrogen-bond interactions
The crystal and molecular structures of sodium pentacyanoammineferrate(II) heptahydrate have been determined by X-ray diffraction. The Fe-N distance is longer than in the analogous iron(III) complex by 0.06 Å; the Fe-C and C-N distances are similar to those for the hexacyanoferrate(II) species, alth...
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| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
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2001
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
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| LEADER | 06314caa a22009977a 4500 | ||
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| 001 | PAPER-1997 | ||
| 003 | AR-BaUEN | ||
| 005 | 20241206083420.0 | ||
| 008 | 190411s2001 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-0035898877 | |
| 024 | 7 | |2 cas |a cyanide, 57-12-5; ferrocyanide, 13408-63-4, 13601-19-9; hydrogen, 12385-13-6, 1333-74-0; sodium ion, 17341-25-2; water, 7732-18-5 | |
| 030 | |a ICHAA | ||
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Parise, A.R. | |
| 245 | 1 | 4 | |a The crystal and molecular structure of sodium pentacyanoammineferrate(II) heptahydrate. Role of intermolecular hydrogen-bond interactions |
| 260 | |c 2001 | ||
| 270 | 1 | 0 | |m Olabe, J.A.; Departamento de Quimica Inorganica, Facultad Ciencias Exactas Naturales, Universidad de Buenos Aires, 1428 Buenos Aires, Argentina; email: olabe@q3.fcen.uba.ar |
| 504 | |a Macartney, D.H., (1988) Rev. Inorg. Chem., 9, p. 101 | ||
| 504 | |a Sharpe, A.G., (1976) The Chemistry of Cyano Complexes of the Transition Metals, , Academic Press New York, (chap. VII) | ||
| 504 | |a Tullberg, A., Vannerberg, N.G., (1974) Acta Chem. Scand., 28, p. 551 | ||
| 504 | |a Gentil, L.A., Navaza, A., Olabe, J.A., Rigotti, G.E., (1991) Inorg. Chim. Acta, 179, p. 89 | ||
| 504 | |a Vannerberg, N.G., (1972) Acta Chem. Scand., 26, p. 2863 | ||
| 504 | |a Bottomley, F., White, P.S., (1979) Acta Crystallogr., Sect. B, 35, p. 2193 | ||
| 504 | |a Vannerberg, N.G., (1974) Acta Chem. Scand., 28, p. 340 | ||
| 504 | |a Marcus, R.A., Sutin, N., (1985) Biochim. Biophys. Acta, 811, p. 265 | ||
| 504 | |a Brunschwig, B.S., Creutz, C., Macartney, D.H., Sham, T.K., Sutin, N., (1982) Faraday Discuss. Chem. Soc., 74, p. 113 | ||
| 504 | |a Kenney, D.J., Flynn, T.P., Gallini, J.B., (1961) J. Inorg. Nucl. Chem., 20, p. 75 | ||
| 504 | |a Frenz, B.A., (1983) Enraf-Nonius Structure Determination Package, , Enraf-Nonius, Delft, The Netherlands | ||
| 504 | |a Sheldrick, G.M., (1990) Acta Crystallogr., Sect. A, 46, p. 467 | ||
| 504 | |a Sheldrick, G.M., (1993) shelxl-93, A Program for Crystal Structure Refinement, , University of Göttingen, Germany | ||
| 504 | |a Johnson, C.K., (1965) ortep, Report ORNL-3794, , Oak Ridge | ||
| 504 | |a Toma, H.E., Malin, J.M., (1974) Inorg. Chem., 13, p. 1772 | ||
| 504 | |a James, A.D., Murray, R.S., Higginson, W.C.E., (1974) J. Chem. Soc., Dalton Trans, p. 1273 | ||
| 504 | |a Holzbecher, M., Knop, O., Falk, M., (1971) Can. J. Chem., 49, p. 1413 | ||
| 504 | |a Srinivas, D., Subramanian, S., (1986) J. Phys. Chem. Solids, 47, p. 731 | ||
| 504 | |a Cheng, Z.N., Wang, J.L., Qiu, J., Miao, F.M., Tang, W.X., (1995) Inorg. Chem., 34, p. 2255 | ||
| 504 | |a Michiels, L.P., Kolks, G., Nesbitt, E.R., Dimauro, P.T., Kirchner, R.M., Waszczak, W., (1985) Inorg. Chim. Acta, 100, p. 211 | ||
| 504 | |a Coe, B.J., Meyer, T.J., White, P.S., (1995) Inorg. Chem., 34, p. 3600 | ||
| 504 | |a Metelski, P.D., Swaddle, T.W., (1999) Inorg. Chem., 38, p. 301 | ||
| 504 | |a Yang, J., Seneviratne, D., Arbatin, G., Andersson, A.M., Curtis, J.C., (1997) J. Am. Chem. Soc., 119, p. 5329 | ||
| 504 | |a Forlano, P., Parise, A.R., Videla, M.R., Olabe, J.A., (1997) Inorg. Chem., 36, p. 5642 | ||
| 506 | |2 openaire |e Política editorial | ||
| 520 | 3 | |a The crystal and molecular structures of sodium pentacyanoammineferrate(II) heptahydrate have been determined by X-ray diffraction. The Fe-N distance is longer than in the analogous iron(III) complex by 0.06 Å; the Fe-C and C-N distances are similar to those for the hexacyanoferrate(II) species, although with a significant relative shortening of the trans Fe-C bonds. The anions display a chain-like arrangement, with interlinking sodium ions and water molecules H-bonded to cyanide N atoms. By comparing with related structures of pentacyano-L-ferrate(II) ions (L = NO+, CN-), it results that the binding mode of the L ligand influences strongly both the first- and second-sphere metal-ligand interactions. © 2001 Elsevier Science B.V. |l eng | |
| 593 | |a Departamento de Química Inorgánica, Analitica y Quim. Fis., INQUIMAE , Fac. de Cie. Exact. y Nat., Univ. de Buenos Aires, Pabellon 2, 1428 Buenos Aires, Argentina | ||
| 593 | |a Departamento de Física, Facultad de Ciencias Exactas, Universidad Nacional de la Plata and IFLP (CONICET), C.C. 67, 1900 La Plata, Argentina | ||
| 593 | |a Instituto de Física de São Carlos, Universidade de São Paulo, C.P. 369, 13560 São Carlos (SP), Brazil | ||
| 593 | |a Corresponding Authors. Tel.:+54-11-45763358, Argentina | ||
| 690 | 1 | 0 | |a AMINE COMPLEXES |
| 690 | 1 | 0 | |a CRYSTAL STRUCTURES |
| 690 | 1 | 0 | |a CYANOFERRATE COMPLEXES |
| 690 | 1 | 0 | |a IRON COMPLEXES |
| 690 | 1 | 0 | |a ANION |
| 690 | 1 | 0 | |a CYANIDE |
| 690 | 1 | 0 | |a FERROCYANIDE |
| 690 | 1 | 0 | |a HYDROGEN |
| 690 | 1 | 0 | |a LIGAND |
| 690 | 1 | 0 | |a METAL ION |
| 690 | 1 | 0 | |a SODIUM DERIVATIVE |
| 690 | 1 | 0 | |a SODIUM ION |
| 690 | 1 | 0 | |a SODIUM PENTACYANOAMMINEFERRATE |
| 690 | 1 | 0 | |a UNCLASSIFIED DRUG |
| 690 | 1 | 0 | |a WATER |
| 690 | 1 | 0 | |a ANALYTIC METHOD |
| 690 | 1 | 0 | |a ARTICLE |
| 690 | 1 | 0 | |a ATOM |
| 690 | 1 | 0 | |a CHEMICAL ANALYSIS |
| 690 | 1 | 0 | |a CHEMICAL STRUCTURE |
| 690 | 1 | 0 | |a CRYSTAL STRUCTURE |
| 690 | 1 | 0 | |a CRYSTALLIZATION |
| 690 | 1 | 0 | |a HYDROGEN BOND |
| 690 | 1 | 0 | |a MOLECULAR INTERACTION |
| 690 | 1 | 0 | |a MOLECULE |
| 690 | 1 | 0 | |a SPECIES |
| 690 | 1 | 0 | |a STRUCTURE ACTIVITY RELATION |
| 690 | 1 | 0 | |a SYNTHESIS |
| 700 | 1 | |a Piro, O.E. | |
| 700 | 1 | |a Castellano, Eduardo Ernesto | |
| 700 | 1 | |a Olabe, J.A. | |
| 773 | 0 | |d 2001 |g v. 319 |h pp. 199-202 |k n. 1-2 |p Inorg. Chim. Acta |x 00201693 |w (AR-BaUEN)CENRE-31 |t Inorganica Chimica Acta | |
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