Reducing sugars effect on available lysine loss of casein by moderate heat treatment

In order to investigate the effect of various reducing sugars on the available lysine loss by Maillard reaction, four model systems were prepared by mixing casein with glucose, fructose, lactose or maltose, followed by storage at 37°C, 50°C and 60°C. The available lysine contents were monitored peri...

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Autor principal: Naranjo, G.B
Otros Autores: Malec, L.S, Vigo, M.S
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1998
Acceso en línea:Registro en Scopus
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LEADER 10871caa a22009497a 4500
001 PAPER-19812
003 AR-BaUEN
005 20230518205111.0
008 190411s1998 xx ||||fo|||| 00| 0 eng|d
024 7 |2 scopus  |a 2-s2.0-0032127597 
024 7 |2 cas  |a casein, 9000-71-9; fructose, 30237-26-4, 57-48-7, 7660-25-5, 77907-44-9; glucose, 50-99-7, 84778-64-3; lactose, 10039-26-6, 16984-38-6, 63-42-3, 64044-51-5; lysine, 56-87-1, 6899-06-5, 70-54-2; maltose, 16984-36-4, 69-79-4 
040 |a Scopus  |b spa  |c AR-BaUEN  |d AR-BaUEN 
030 |a FOCHD 
100 1 |a Naranjo, G.B. 
245 1 0 |a Reducing sugars effect on available lysine loss of casein by moderate heat treatment 
260 |c 1998 
270 1 0 |m Naranjo, G.B.; Departamento de Quimica Organica, Facultad Ciencias Exactas Naturales, Universidad de Buenos Aires, Pabellon 2, 1428-Buenos Aires, Argentina 
506 |2 openaire  |e Política editorial 
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504 |a Goodno, C.C., Swaisgood, H.E., Catignani, G.L., A fluorimetric assay for available lysine in proteins (1981) Analytical Biochemistry, 115, pp. 325-328 
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504 |a Labuza, T.P., Application of chemical kinetics to deterioration of foods (1984) Journal of Chemical Education, 61, pp. 348-358 
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504 |a Thompson, D.R., Wolf, J.C., Available lysine losses in a real food system (1979) Transactions of the ASAE, 22, pp. 202-206 
504 |a Vigo, M.S., Malec, L.S., Gómez, R.G., Llosa, R.A., Spectrophotometric assay using o-phthalaldehyde for determination of available lysine in dairy products (1992) Food Chemistry, 44, pp. 363-365 
504 |a Warmbier, H.C., Schnickels, R.A., Labuza, T.P., Non-enzymatic browning kinetics in an intermediate moisture model system: Effect of glucose to lysine ratio (1976) Journal of Food Science, 41, pp. 981-983 
504 |a Warren, R.M., Labuza, T.P., Comparison of chemically measured available lysine with relative nutritive value measured by a Tetrahymena bioassay during early stages of nonenzymatic browning (1977) Journal of Food Science, 42, pp. 429-431 
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504 |a Wolf, J.C., Thompson, D.R., Reineccius, G.A., Initial losses of available lysine in model systems (1977) Journal of Food Science, 42, pp. 1540-1544 
504 |a Wolf, J.C., Thompson, D.R., Reineccius, G.A., Comparison between model predictions and measured values for available lysine losses in a model food system (1978) Journal of Food Science, 43, pp. 1486-1490 
504 |a Wolf, J.C., Thompson, D.R., Reineccius, G.A., Predicting available lysine losses during heal processing (1982) Journal of Food Processing and Engineering, 6, pp. 201-218 
504 |a Yaylayan, V.A., Ismail, A.A., Mandeville, S., Quantitative determination of the effect of pH and temperature on the keto form of D-fructose by FT IR spectroscopy (1993) Carbohydrate Research, 248, pp. 355-360 
520 3 |a In order to investigate the effect of various reducing sugars on the available lysine loss by Maillard reaction, four model systems were prepared by mixing casein with glucose, fructose, lactose or maltose, followed by storage at 37°C, 50°C and 60°C. The available lysine contents were monitored periodically. Highest and lowest reaction rates were observed in the model systems containing glucose and fructose, respectively, at the three temperatures. The two disaccharides behaved very similarly, with reaction rates between those of the monosaccharides studied. The activation energies of glucose, lactose and maltose systems were similar (116-132 kJmol-1), while that of fructose was somewhat higher (166 kJmol-1). This difference was supposed to be in part due to the different mechanism of tautomerization of fructose, highly dependent on temperature. Therefore, though the potential nutritional damage at moderate temperatures is lower when fructose is used instead of other reducing sugars, its higher activation energy can reverse the effect at higher temperatures.  |l eng 
536 |a Detalles de la financiación: Secretaría de Ciencia y Técnica, Universidad de Buenos Aires 
536 |a Detalles de la financiación: This work was financials upportedb y grant UBACYT No. EX178 from Secretariad e Ciencia y Tecnica de la Universidadd e BuenosA ires. 
593 |a Depto. de Quimica Orgánica, Universidad de Buenos Aires, Ciudad Universitaria, 1428-Buenos Aires, Argentina 
690 1 0 |a CASEIN 
690 1 0 |a FRUCTOSE 
690 1 0 |a GLUCOSE 
690 1 0 |a LACTOSE 
690 1 0 |a LYSINE 
690 1 0 |a MALTOSE 
690 1 0 |a SUGAR 
690 1 0 |a ARTICLE 
690 1 0 |a FOOD PROCESSING 
690 1 0 |a FOOD STORAGE 
690 1 0 |a GLYCATION 
690 1 0 |a HEATING 
690 1 0 |a TEMPERATURE 
700 1 |a Malec, L.S. 
700 1 |a Vigo, M.S. 
773 0 |d 1998  |g v. 62  |h pp. 309-313  |k n. 3  |p Food Chem.  |x 03088146  |w (AR-BaUEN)CENRE-312  |t Food Chemistry 
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856 4 0 |u https://hdl.handle.net/20.500.12110/paper_03088146_v62_n3_p309_Naranjo  |y Handle 
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