Effect of mineral matter removal on pyrolysis of wood sawdust from an invasive species

Kinetics of the pyrolysis of wood sawdust from the invasive species Parkinsonia aculeata, untreated and demineralized by a mild acid treatment, is comparatively investigated in order to examine the effect of the removal of minerals naturally present in the biomass. Non-isothermal thermogravimetric a...

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Autor principal: Messina, L.G
Otros Autores: Bonelli, P.R, Cukierman, A.L
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: Taylor and Francis Inc. 2016
Acceso en línea:Registro en Scopus
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024 7 |2 scopus  |a 2-s2.0-84959065420 
040 |a Scopus  |b spa  |c AR-BaUEN  |d AR-BaUEN 
100 1 |a Messina, L.G. 
245 1 0 |a Effect of mineral matter removal on pyrolysis of wood sawdust from an invasive species 
260 |b Taylor and Francis Inc.  |c 2016 
270 1 0 |m Cukierman, A.L.; Prog. de Invest. y Desarrollo de Fuentes Alternativas de Materias Primas y Ener. - Depto. de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón de Industrias, 2620, Ciudad Universitaria, Argentina; email: analea@di.fcen.uba.ar 
506 |2 openaire  |e Política editorial 
504 |a Basso, M.C., Cukierman, A.L., Wastewater treatment by chemically activated carbons from giant reed: Effect of the activation atmosphere on properties and adsorptive behavior (2006) Sep. Sci. Technol, 41, pp. 149-156 
504 |a Bonelli, P.R., Nunell, G., Fernández, M.E., Buonomo, E.L., Cukierman, A.L., The potential applications of the bio-char derived from the pyrolysis of an agro-industrial waste Effects of temperature and acid-pretreatment (2012) Energy Sources Part A, 34, pp. 746-755 
504 |a Bridgwater, A.V., Review of fast pyrolysis of biomass and product upgrading (2012) Biomass Bioenergy, 38, pp. 68-94 
504 |a Chew, J.J., Doshi, V., Recent advances in biomass pretreatment-Torrefaction fundamentals and technology (2011) Renewable Sustainable Energy Rev, 15, pp. 4212-4222 
504 |a De Lange, W.J., Stafford, W.H.L., Forsyth, G.G., Le Maitre, D.C., Incorporating stakeholder preferences in the selection of technologies for using invasive alien plants as a bio-energy feedstock: Applying the analytical hierarchy process (2012) J. Environ. Manage, 99, pp. 76-83 
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504 |a Eom, I.-Y., Kim, J.-Y., Kim, T.-S., Lee, S.-M., Choi, D., Choi, I.-G., Choi, J.-W., Effect of essential inorganic metals on primary thermal degradation of lignocellulosic biomass (2012) Bioresour. Technol, 104, pp. 687-694 
504 |a Fahmi, R., Bridgwater, A.V., Donnison, I., Yates, N., Jones, J.M., The effect of lignin and inorganic species in biomass pyrolysis oil yields, quality and stability (2008) Fuel, 87, pp. 1230-1240 
504 |a González, J.D., Kim, M.R., Buonomo, E.L., Bonelli, P.R., Cukierman, A.L., Pyrolysis of biomass from sustainable energy plantations: Effect of mineral matter reduction on kinetics and charcoal pore structure (2008) Energy Sources Part A, 30, pp. 809-817 
504 |a Nunell, G.V., Fernández, M.E., Bonelli, P.R., Cukierman, A.L., Conversion of biomass from an invasive species into activated carbons for removal of nitrate from wastewater (2012) Biomass Bioenergy, 44, pp. 87-95 
504 |a Qu, T., Guo, W., Shen, L., Xiao, J., Zhao, K., Experimental study of biomass pyrolysis based on three major components: Hemicellulose, cellulose and lignin (2011) Ind. Eng. Chem. Res, 50, pp. 10424-10433 
504 |a Raveendran, K., Ganesh, A., Khilar, K.C., Influence of mineral matter on biomass pyrolysis characteristics (1995) Fuel, 74, pp. 1812-1822 
504 |a Saidur, R., Abdelaziz, E.A., Demirbas, A., Hossain, M.S., Mekhilef, S., A review on biomass as a fuel for boilers (2011) Renewable Sustainable Energy Rev, 15, pp. 2262-2289 
504 |a Shi, L., Yu, S., Wang, F.-C., Wang, J., Pyrolytic characteristics of rice straw and its constituents catalyzed by internal alkali and alkali earth metals (2012) Fuel, 96, pp. 586-594 
520 3 |a Kinetics of the pyrolysis of wood sawdust from the invasive species Parkinsonia aculeata, untreated and demineralized by a mild acid treatment, is comparatively investigated in order to examine the effect of the removal of minerals naturally present in the biomass. Non-isothermal thermogravimetric analysis from room temperature up to 500°C is applied for this purpose. Demineralization shifts the process onset and the maximum degradation rate to higher temperatures, and leads to enhance the activation energy from 56 to 60 kJ mol-1, pointing to a catalytic role of alkaline and alkaline earth metals in the biomass. Likewise, the three kinds of pyrolysis products (gas, bio-char, and bio-oil) are obtained from experiments performed in a bench-scale installation at 500°C. Yields and physicochemical characteristics of the pyrolysis products are determined. The pronounced reduction in the content of metals in the sawdust leads to increase bio-oil yield in around 10%, the specific surface area of the bio-char, from ≈ 2 to ≈ 74 m2 g-1, and the higher heating value of all the pyrolysis products. © 2016 Taylor & Francis.  |l eng 
593 |a Prog. de Invest. y Desarrollo de Fuentes Alternativas de Materias Primas y Ener. - Depto. de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón de Industrias, 2620, Ciudad Universitaria, Buenos Aires, C1428BGA, Argentina 
593 |a Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires, Argentina 
593 |a Cátedra de Tecnología Farmacéutica II, Departamento de Tecnología Farmacéutica, Facultad de Farmacia y Bioquímica, Universidad de Buenos Aires, Buenos Aires, Argentina 
690 1 0 |a BIO-ENERGY 
690 1 0 |a BIO-FUELS 
690 1 0 |a BIORESOURCES 
690 1 0 |a INVASIVE WOOD BIOMASS 
690 1 0 |a PYROLYSIS 
690 1 0 |a ACTIVATION ENERGY 
690 1 0 |a BIOFUELS 
690 1 0 |a BIOMASS 
690 1 0 |a CALORIFIC VALUE 
690 1 0 |a DEGRADATION 
690 1 0 |a THERMOGRAVIMETRIC ANALYSIS 
690 1 0 |a WOOD FUELS 
690 1 0 |a BIO ENERGY 
690 1 0 |a BIORESOURCES 
690 1 0 |a HIGHER HEATING VALUE 
690 1 0 |a INVASIVE SPECIES 
690 1 0 |a PARKINSONIA ACULEATA 
690 1 0 |a PHYSICOCHEMICAL CHARACTERISTICS 
690 1 0 |a PYROLYSIS PRODUCTS 
690 1 0 |a WOOD BIOMASS 
690 1 0 |a PYROLYSIS 
700 1 |a Bonelli, P.R. 
700 1 |a Cukierman, A.L. 
773 0 |d Taylor and Francis Inc., 2016  |g v. 38  |h pp. 542-548  |k n. 4  |p Energy Sources Recovery Util. Environ. Eff.  |x 15567036  |t Energy Sources, Part A: Recovery, Utilization and Environmental Effects 
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