A distinct tetradentate N2O2-type ligand: (o-Carboranyl)bis(2-hydroxymethyl)pyridine

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A new chiral racemic ligand (o-carboranyl)bis(2-hydroxymethyl)pyridine oCB(hmpH)2, that is composed of a central o-carborane unit where two arms radiate out of the cluster carbons each one containing a 2-pyridylmethylalcohol chelating arms, provides two potentially bidentate {NO} or one tetradentate...

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Detalles Bibliográficos
Autor principal: Di Salvo, F.
Otros Autores: Teixidor, F., Viñas, C., Giner Planas, J.
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2013
Acceso en línea:Registro en Scopus
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Aporte de:Registro referencial: Solicitar el recurso aquí
Biblioteca Central Dr. Luis F. Leloir (FCEN) de Universidad de Buenos Aires
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100 1 |a Di Salvo, F. 
245 1 2 |a A distinct tetradentate N2O2-type ligand: (o-Carboranyl)bis(2-hydroxymethyl)pyridine 
260 |c 2013 
270 1 0 |m Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus U.A.B, 08193 Bellaterra, Spain 
506 |2 openaire  |e Política editorial 
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520 3 |a A new chiral racemic ligand (o-carboranyl)bis(2-hydroxymethyl)pyridine oCB(hmpH)2, that is composed of a central o-carborane unit where two arms radiate out of the cluster carbons each one containing a 2-pyridylmethylalcohol chelating arms, provides two potentially bidentate {NO} or one tetradentate {N2O2} binding pockets. An unprecedented octahedral CoII complex [CoCl2(anti- oCB(hmpH)2] was obtained under aerobic conditions and characterized by X-ray crystallography as well as IR and NMR spectroscopy. anti-oCB(hmpH) 2 acts as a tetradentate N2O2-ligand affording the complex as a racemic mixture of cis-α Δ-[CoCl2( RRanti-oCB(hmpH)2)] and Λ-[CoCl2( SSanti-oCB(hmpH)2)]. The new ligand oCB(hmpH)2 appears to be suitable for producing a variety of new chiral-at-metal complexes. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.  |l eng 
593 |a Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus U.A.B, 08193 Bellaterra, Spain 
593 |a Departamento de Química Inorgánica, Analítica, y Química Física, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, Pabellõn 2, C1428EHA Buenos Aires, Argentina 
690 1 0 |a BORON CLUSTERS 
690 1 0 |a CARBORANYLALCOHOLS 
690 1 0 |a CHIRAL LIGANDS 
690 1 0 |a COBALT 
690 1 0 |a SELF-ASSEMBLY 
700 1 |a Teixidor, F. 
700 1 |a Viñas, C. 
700 1 |a Giner Planas, J. 
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856 4 0 |u https://doi.org/10.1002/zaac.201300116  |y DOI 
856 4 0 |u https://hdl.handle.net/20.500.12110/paper_00442313_v639_n7_p1194_DiSalvo  |y Handle 
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