Conjugate additions of furylcuprates to α-enones. The effect of the copper precursor and of TMSCl used as additive

The addition of organocuprates to α,β-unsaturated substrates, namely E-cinamaldehyde and 2-cyclohexen-1-one, was studied in THF. The furan moiety was chosen for the heterocuprate, because the methods for the synthesis of furan derivatives are scarce and they have a strong potentiality for tandem rea...

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Detalles Bibliográficos
Autores principales: Rodríguez, C., Vázquez, Á., Nudelman, N.S.
Formato: JOUR
Materias:
Conjugated addition
Furyllithium
Organocuprates
TMSCl
α,β- unsaturated carbonyl compound
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_1551-701_v2008_n6_p140_Rodriguez
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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