ZnII-promoted D-homorearrangement of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde

The synthesis of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde and a highly efficient method for its D-homorearrangement is described. The transformation produced by the action of Zn IIafforded 17α-hydroxy-3β-methoxy-D-homoandrost-5-en-17a-one in a fast, stereospecific, and high-yield reactio...

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Autores principales: Schor, L., Gros, E.G., Seldes, A.M.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_14704358_v_n4_p453_Schor
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