ZnII-promoted D-homorearrangement of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde
The synthesis of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde and a highly efficient method for its D-homorearrangement is described. The transformation produced by the action of Zn IIafforded 17α-hydroxy-3β-methoxy-D-homoandrost-5-en-17a-one in a fast, stereospecific, and high-yield reactio...
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| Autores principales: | , , |
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| Formato: | JOUR |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_14704358_v_n4_p453_Schor |
| Aporte de: |
| Sumario: | The synthesis of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde and a highly efficient method for its D-homorearrangement is described. The transformation produced by the action of Zn IIafforded 17α-hydroxy-3β-methoxy-D-homoandrost-5-en-17a-one in a fast, stereospecific, and high-yield reaction. © Royal Society of Chemistry. |
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