Tracing the Iron Nitrosyl Complex [Fe(2,2'-bipyridine)(CN)3(NO)]-

Mostrar todas las versiones(2)

The previously reported complex [Ph4P][Fe(bpy)(CN)3(NO)] (bpy = 2,2'-bipyridine) was synthesised and characterised in detail using UV/Vis absorption and IR spectroscopy, cyclic voltammetry, and single-crystal XRD. Detailed spectroelectrochemical (UV/Vis, IR and EPR) insight adds perfectly to th...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Foi, A., Di Salvo, F., Doctorovich, F., Roy, T.G., Stirnat, K., Biewer, C., Klein, A.
Formato: INPR
Materias:
Di-imines
Electrochemistry
IR spectroscopy
Iron
Nitrogen oxides
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_14341948_v_n_p_Foi
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
Descripción
Sumario:The previously reported complex [Ph4P][Fe(bpy)(CN)3(NO)] (bpy = 2,2'-bipyridine) was synthesised and characterised in detail using UV/Vis absorption and IR spectroscopy, cyclic voltammetry, and single-crystal XRD. Detailed spectroelectrochemical (UV/Vis, IR and EPR) insight adds perfectly to the previous electrochemical characterisation of this complex. The description of this {Fe(NO)}7 complex as a low-spin FeII-NO· system based on the spectroscopic results is supported by DFT calculations. Reversible oxidation leads to the corresponding {Fe(NO)}6 (FeII-NO+) complex, whereas the reduction to the formal {Fe(NO)}8 species [presumably (FeII-NO-)] occurs irreversibly. When trying to synthesise further derivatives that contain other α-diimine ligands, only for the 1,10-phenanthroline (phen) derivative were some results obtained. For other ligands the obtained materials were too reactive. The reasons for such behaviour are also discussed. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Ejemplares similares