Unusual solvent effects in the reactions of 1-halo-2,4-dinitrobenzenes andaniline in aprotic and dipolar-aprotic solvents. Effects of aggregates
The kinetics of reactions between 1-halogeno-2,4-dinitrobenzene (halogen = F, Cl) and aniline were studied in toluene, acetone, dimethylsulfoxide and in toluene-acetone mixtures. Unexpectedly, when chlorine is the nucleofugue, the second rate coefficients, kA, in toluene shows a parabolic dependence...
Guardado en:
| Autores principales: | Alvaro, C.E.S., Nudelman, N.S. |
|---|---|
| Formato: | JOUR |
| Materias: | |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_14246376_v2003_n10_p95_Alvaro |
| Aporte de: |
Ejemplares similares
-
Unusual solvent effects in the reactions of 1-halo-2,4-dinitrobenzenes andaniline in aprotic and dipolar-aprotic solvents. Effects of aggregates
Publicado: (2003) -
Effects of the nucleophile structure on the mechanisms of reaction of 1-chloro-2,4-dinitrobenzene with aromatic amines in aprotic solvents
por: Nudelman, N.S., et al. -
Effects of the nucleophile structure on the mechanisms of reaction of 1-chloro-2,4-dinitrobenzene with aromatic amines in aprotic solvents
Publicado: (1999) -
Hydrogen-bonded nucleophile effects in ANS: The reactions of 1-chloro and 1-fluoro-2,4-dinitrobenzene with 2-guanidinobenzimidazole, 1-(2-aminoethyl) piperidine and N-(3-aminopropyl)morpholine in aprotic solvents
por: Alvaro, C.E.S., et al. -
Hydrogen-bonded nucleophile effects in ANS: The reactions of 1-chloro and 1-fluoro-2,4-dinitrobenzene with 2-guanidinobenzimidazole, 1-(2-aminoethyl) piperidine and N-(3-aminopropyl)morpholine in aprotic solvents
Publicado: (2011)