Enantioselective addition of Grignard reagents to aldehydes

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The addition of Grignard reagents to aldehydes in the presence of chiral aminoal-cohols shows a moderate enantioselectivity. The study carried out with a series of ligands allows the correlation between the structural characteristics and their reactivity.

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Detalles Bibliográficos
Autores principales: Englebienne, P., Schulz, H., Nudelman, N.
Formato: JOUR
Materias:
aldehyde
reagent
addition reaction
analytic method
chirality
conference paper
enantioselectivity
Grignard reaction
reaction analysis
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_14203049_v5_n3_p598_Englebienne
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
Descripción
Sumario:The addition of Grignard reagents to aldehydes in the presence of chiral aminoal-cohols shows a moderate enantioselectivity. The study carried out with a series of ligands allows the correlation between the structural characteristics and their reactivity.

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