Lipase-catalysed deacetylation of androstane and pregnane derivatives: Influence of ring D substitution

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A series of acetoxy derivatives of androstane and pregnane was deacetylated in organic solvents by microbial lipases. The best results were obtained with lipase from Candida antarctica (CAL B), Candida rugosa (CRL) and Pseudomonas sp. (PSL). In some derivatives, CAL B and CRL showed a regioselective...

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Detalles Bibliográficos
Autores principales: Bruttomesso, A.C., Baldessari, A.
Formato: JOUR
Materias:
Androstane
Lipase-catalysed deacetylation
Pregnane
Acetylation
Carbon
Catalysis
Derivatives
Organic solvents
Substitution reactions
Enzymes
acetic acid derivative
bacterial enzyme
carbon
organic solvent
prasterone
pregnane derivative
steroid
triacylglycerol lipase
atom
Candida antarctica
Candida rugosa
catalysis
chemical bond
conference paper
deacetylation
hybridization
microorganism
Pseudomonas
stereochemistry
Candida
Pseudomonas sp.
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_13811177_v29_n1-6_p149_Bruttomesso
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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