Dynamical aspects of isomerization and melting transitions in [H2O]8

We present a transition path sampling study of the dynamics of isomerization between the S4 and the D2d cubic structures of the water octamer. The reaction mechanism involves a transition state characterized by a distorted face exhibiting a diagonal hydrogen bond. Analysis of an ensemble of trajecto...

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Autores principales: Laria, D., Rodriguez, J., Dellago, C., Chandler, D.
Formato: JOUR
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_10895639_v105_n12_p2646_Laria
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