Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene
The thermal addition of CF3OF to CF2CC12 has been studied between -7.0 and 29.7 °C. The pressure of CF3OF was varied between 6.4 and 196.7 Torr and that of CF2CC12 between 5.4 and 203 Torr. CF3CC12F, CF3o(CF2CC12)F and CF3o(CF2CCl2)1oCF3, where i = 2,3 … n, were the products. Above 110 Torr of olefi...
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| Autores principales: | , |
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| Formato: | JOUR |
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_09429352_v158_nPart_1_p25_DosSantosAfonso |
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| Sumario: | The thermal addition of CF3OF to CF2CC12 has been studied between -7.0 and 29.7 °C. The pressure of CF3OF was varied between 6.4 and 196.7 Torr and that of CF2CC12 between 5.4 and 203 Torr. CF3CC12F, CF3o(CF2CC12)F and CF3o(CF2CCl2)1oCF3, where i = 2,3 … n, were the products. Above 110 Torr of olefin, non-volatile condensate appeared. © by R. Oldenbourg Verlag |
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