Synthesis of highly hindered 1,2-diaryl diketones and of cis- and trans-1,2-diacetoxy-1,2-bis(aryl)ethenes
Highly hindered 1,2-diaryl diketones can be synthesized in good yields by the reaction of 1-aryllithium with CO in THF solution at atmospheric pressure; preparation of cis- and trans-1,2-diacetoxy-1,2-bis(Mes)ethene can be also afforded by a similar procedure and further quenching with Ac2O.
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| Formato: | JOUR |
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_03082342_v_n7_p422_Nudelman |
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todo:paper_03082342_v_n7_p422_Nudelman2023-10-03T15:22:49Z Synthesis of highly hindered 1,2-diaryl diketones and of cis- and trans-1,2-diacetoxy-1,2-bis(aryl)ethenes Nudelman, N. Schulz, H. 1,2 dicarbonyl derivative carbon monoxide ethylene derivative lithium derivative article cis trans isomerism cross linking stereospecificity synthesis Highly hindered 1,2-diaryl diketones can be synthesized in good yields by the reaction of 1-aryllithium with CO in THF solution at atmospheric pressure; preparation of cis- and trans-1,2-diacetoxy-1,2-bis(Mes)ethene can be also afforded by a similar procedure and further quenching with Ac2O. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_03082342_v_n7_p422_Nudelman |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
1,2 dicarbonyl derivative carbon monoxide ethylene derivative lithium derivative article cis trans isomerism cross linking stereospecificity synthesis |
| spellingShingle |
1,2 dicarbonyl derivative carbon monoxide ethylene derivative lithium derivative article cis trans isomerism cross linking stereospecificity synthesis Nudelman, N. Schulz, H. Synthesis of highly hindered 1,2-diaryl diketones and of cis- and trans-1,2-diacetoxy-1,2-bis(aryl)ethenes |
| topic_facet |
1,2 dicarbonyl derivative carbon monoxide ethylene derivative lithium derivative article cis trans isomerism cross linking stereospecificity synthesis |
| description |
Highly hindered 1,2-diaryl diketones can be synthesized in good yields by the reaction of 1-aryllithium with CO in THF solution at atmospheric pressure; preparation of cis- and trans-1,2-diacetoxy-1,2-bis(Mes)ethene can be also afforded by a similar procedure and further quenching with Ac2O. |
| format |
JOUR |
| author |
Nudelman, N. Schulz, H. |
| author_facet |
Nudelman, N. Schulz, H. |
| author_sort |
Nudelman, N. |
| title |
Synthesis of highly hindered 1,2-diaryl diketones and of cis- and trans-1,2-diacetoxy-1,2-bis(aryl)ethenes |
| title_short |
Synthesis of highly hindered 1,2-diaryl diketones and of cis- and trans-1,2-diacetoxy-1,2-bis(aryl)ethenes |
| title_full |
Synthesis of highly hindered 1,2-diaryl diketones and of cis- and trans-1,2-diacetoxy-1,2-bis(aryl)ethenes |
| title_fullStr |
Synthesis of highly hindered 1,2-diaryl diketones and of cis- and trans-1,2-diacetoxy-1,2-bis(aryl)ethenes |
| title_full_unstemmed |
Synthesis of highly hindered 1,2-diaryl diketones and of cis- and trans-1,2-diacetoxy-1,2-bis(aryl)ethenes |
| title_sort |
synthesis of highly hindered 1,2-diaryl diketones and of cis- and trans-1,2-diacetoxy-1,2-bis(aryl)ethenes |
| url |
http://hdl.handle.net/20.500.12110/paper_03082342_v_n7_p422_Nudelman |
| work_keys_str_mv |
AT nudelmann synthesisofhighlyhindered12diaryldiketonesandofcisandtrans12diacetoxy12bisarylethenes AT schulzh synthesisofhighlyhindered12diaryldiketonesandofcisandtrans12diacetoxy12bisarylethenes |
| _version_ |
1807323473443291136 |