Structure and reactivity of copper (II) carboxylates I. Copper (II) dipicolinates

The crystal and molecular structures of a series of salts formed by copper (II) with dipicolinic acid were used to interpret the dehydration behavior. The morphology of single crystals dehydration of Cu(dipic)·2H2O (monoclinic and triclinic symmetry), Cu(dipic)·3H2O and Cu(dipic) (H2dipic)·xH2O was...

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Autores principales: Sileo, E.E., Quinteros-Rivero, M.F., Rivero, B.E., Rigotti, G., Blesa, M.A.
Formato: JOUR
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_01672738_v73_n1-2_p153_Sileo
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Sumario:The crystal and molecular structures of a series of salts formed by copper (II) with dipicolinic acid were used to interpret the dehydration behavior. The morphology of single crystals dehydration of Cu(dipic)·2H2O (monoclinic and triclinic symmetry), Cu(dipic)·3H2O and Cu(dipic) (H2dipic)·xH2O was shown to be governed by the arrangement of water molecules along specific orientations. © 1994.