Ring expansion of fused cyclopropylketones. Synthesis of a 12(13→18)-abeo-pregnane

A synthetic approach to 12(13→18)-abeo-pregnanes by base catalyzed rearrangement of a 12,18-cyclopregnane-11,20-dione is described. The latter steroid was prepared by means of a hypoiodite type reaction.

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Detalles Bibliográficos
Autores principales: Ferrara, A., Burton, G.
Formato: JOUR
Materias:
pregnane derivative
article
drug synthesis
reaction analysis
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00404039_v37_n7_p929_Ferrara
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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