Lipoxygenase-catalyzed dehydration of furylhydroperoxides

3-alkoxycarbonyl-5(1-hydroperoxyalkyl)-furans 1 are changed into the corresponding 5-acyl and 5-formyl derivatives 2 by a lipoxygenase-catalyzed process. The conversion shows to proceed in enantioselective way leading to chiral furylhydroperoxides and furylalcohols. 3-alkoxycarbonyl-5(1-hydroperoxya...

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Detalles Bibliográficos
Autores principales: Antonioletti, R., Bonadies, F., Monteagudo, E.S., Rossi, A., Scettri, A.
Formato: JOUR
Materias:
furan derivative
lipoxygenase
article
enzyme activity
priority journal
reaction analysis
synthesis
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00404039_v33_n14_p1919_Antonioletti
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
Descripción
Sumario:3-alkoxycarbonyl-5(1-hydroperoxyalkyl)-furans 1 are changed into the corresponding 5-acyl and 5-formyl derivatives 2 by a lipoxygenase-catalyzed process. The conversion shows to proceed in enantioselective way leading to chiral furylhydroperoxides and furylalcohols. 3-alkoxycarbonyl-5(1-hydroperoxyalkyl)-furans 1 are changed into the corresponding 5-acyl and 5-formyl derivatives 2 by a lipoxygenase-catalyzed process. © 1992.

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