Ultra-fast dynamics in Coumarin 153 obtained by differential fluorescence
We present measurements of the molecular rotational diffusion dynamics in the picosecond scale in a Coumarin 153 ethylene-glycol solution. A novel technique is used in which the fluorescent sample is excited with two femtosecond laser pulses in a pump and probe scheme. The spatial anisotropy generat...
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| Autores principales: | , , , |
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| Formato: | JOUR |
| Materias: | |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00304018_v195_n1-4_p215_Torga |
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| Sumario: | We present measurements of the molecular rotational diffusion dynamics in the picosecond scale in a Coumarin 153 ethylene-glycol solution. A novel technique is used in which the fluorescent sample is excited with two femtosecond laser pulses in a pump and probe scheme. The spatial anisotropy generated by the first pulse excitation is sampled as a function of delay time through the fluorescence produced by the delayed pulse. The rotational time is obtained from the change in the fluorescence produced as a function of the delay time. © 2001 Elsevier Science B.V. All rights reserved. |
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