Photochemical Reaction of (-)-Quebrachamine. Unusual Photoformation of an Ibogamine-like Ring System
Irradiation of (-)-quebrachamine, a C4N-C5N-C6-C8N four-ring system, gives a 16-hydroxy derivative of a C4N-C5N-C6-C6-C6N five-ring system (a 16-hydroxy derivative of an ibogamine-like ring system). Some aspects of the photohydroxy cyclization reaction are discussed. © 1989, American Chemical Societ...
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| Autores principales: | , |
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| Formato: | JOUR |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00223263_v54_n13_p3174_Postigo |
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| Sumario: | Irradiation of (-)-quebrachamine, a C4N-C5N-C6-C8N four-ring system, gives a 16-hydroxy derivative of a C4N-C5N-C6-C6-C6N five-ring system (a 16-hydroxy derivative of an ibogamine-like ring system). Some aspects of the photohydroxy cyclization reaction are discussed. © 1989, American Chemical Society. All rights reserved. |
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