A study of substituent effect on1H and13C NMR spectra of mono, di and poly substituted carbazoles
1H and 13C NMR spectra of several substituted carbazoles (Series 1, 2, 3, 4 and 5) were measured. Substituent chemical shifts (SCS's) and Lynch correlations of 1H and 13C nuclei were calculated and the substituent effect on the NMR phenomena was determined. Atomic charge densities for carbazole...
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| Autores principales: | , , |
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| Formato: | JOUR |
| Materias: | |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_0022152X_v42_n5_p867_Bonesi |
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| Sumario: | 1H and 13C NMR spectra of several substituted carbazoles (Series 1, 2, 3, 4 and 5) were measured. Substituent chemical shifts (SCS's) and Lynch correlations of 1H and 13C nuclei were calculated and the substituent effect on the NMR phenomena was determined. Atomic charge densities for carbazoles of Series 1, 2, 3, 4 and 5 were calculated by using the semi empirical PM3 method. These values also show a linear correlation with the 13C chemical shifts. |
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